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首页> 外文期刊>Crystal growth & design >Crystal growth and single-crystal structures of RERhO3 (RE = La, Pr, Nd, Sm, Eu, Tb) orthorhodites from a K2CO3 flux
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Crystal growth and single-crystal structures of RERhO3 (RE = La, Pr, Nd, Sm, Eu, Tb) orthorhodites from a K2CO3 flux

机译:由K2CO3助熔剂形成的RERhO3(RE = La,Pr,Nd,Sm,Eu,Tb)正长晶石的晶体生长和单晶结构

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摘要

Single crystals of LaRhO3, PrRhO3, NdRhO3, SmRhO3, EuRhO3, and TbRhO3 have been grown for the first time using a K2CO3 flux. All the compounds were found to crystallize in the orthorhombic space group Pbnm (No. 62) and adopt the GdFeO3 distorted perovskite structure type. Transition toward a pseudo-cubic cell is noted as the rare earth cation size increases.
机译:LaRhO3,PrRhO3,NdRhO3,SmRhO3,EuRhO3和TbRhO3的单晶首次使用K2CO3助熔剂生长。发现所有化合物均在正交空间群Pbnm(第62号)中结晶,并采用GdFeO3扭曲的钙钛矿结构类型。随着稀土阳离子尺寸的增加,注意到向伪立方电池的过渡。

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