Unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) net constructed by trinuclear mixed-valence cobalt clusters

Zhang XM; Zheng YZ; Li CR; Zhang WX; Chen XM

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Unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) net constructed by trinuclear mixed-valence cobalt clusters

机译：由三核混合价钴簇构建的前所未有的（3,9）-连通（4（2）.6）（3）（4（6）.6（21）.8（9））网

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A solvothermal reaction of Co2O3, CoSO4, pyridine-3,5-dicarboxylic acid, and H2O2 in an aqueous MeCN solution yielded a three-dimensional coordination framework [Co-3(OH)(pdc)(3)]center dot H2O (1) (pdc = pyridine-3,5-dicarboxylate). Compound 1 shows an unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) topology in which hydroxycentered mixed-valence Co-3(OH)(CO2)(6) clusters act as nine-connected nodes of a tricapped trigonal prism, and pdc groups act as three-connected nodes of trigonal geometry.

机译：Co2O3，CoSO4，吡啶3,5-二羧酸和H2O2在MeCN水溶液中的溶剂热反应产生三维配位骨架[Co-3（OH）（pdc）（3）]中心点H2O（1 ）（pdc = 3,5-二羧酸吡啶）。化合物1显示了前所未有的（3,9）连接的（4（2）.6）（3）（4（6）.6（21）.8（9））拓扑，其中羟基中心混合价Co-3（ OH）（CO2）（6）簇充当三角形三角棱镜的九个连接节点，而pdc组充当三角形几何的三连接节点。

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来源
《Crystal growth & design》 |2007年第5期|共4页
作者
Zhang XM; Zheng YZ; Li CR; Zhang WX; Chen XM;
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正文语种 eng
中图分类晶体学;
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COORDINATION POLYMERS; ELECTRON-TRANSFER; SOLID-STATE; SPIN FRUSTRATION; PHASE-TRANSITION; 3-PERIODIC NETS; CRYSTAL; IRON; FRAMEWORKS; CHEMISTRY;

机译：配位聚合物;电子转移;固态;自旋碎变;相变;3-周期网;晶体;铁;框架;化学性质;

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1. Unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) net constructed by trinuclear mixed-valence cobalt clusters [J] . Zhang XM, Zheng YZ, Li CR, Crystal growth & design . 2007,第5期

机译：由三核混合价钴簇构建的前所未有的（3,9）-连通（4（2）.6）（3）（4（6）.6（21）.8（9））网
2. Unprecedented(3,10)-Connected 2-D Metal-Organic Framework Constructed from Octanuclear Cobalt(II)Clusters and a New Bifunctional Ligand [J] . Wen-Qiang Zou, Ming-Sheng Wang, Yan Li Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第17期

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Unprecedented (3,9)-connected (4(2).6)(3)(4(6).6(21).8(9)) net constructed by trinuclear mixed-valence cobalt clusters

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