Ionic Conductivity of AgBaSc(VO4)(2) Crystals with Glaserite-Type Structure

Sorokin N. I.

首页> 外文期刊>Crystallography reports >Ionic Conductivity of AgBaSc(VO4)(2) Crystals with Glaserite-Type Structure

【24h】

Ionic Conductivity of AgBaSc(VO4)(2) Crystals with Glaserite-Type Structure

机译：Agbasc（VO4）（2）晶体与葡萄矾型结构的离子电导率

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The electrical conductivity sigma(dc) of AgBaSc(VO4)(2) vanadate crystals with glaserite structure (K3Na(SO4)(2) type, sp. gr. Pm1) has been investigated by impedance spectroscopy in the frequency range of 5-5x10(5) Hz and at temperatures from 505 to 835 K. A jump in the sigma(dc) value by a factor of similar to 2.5 is observed at 700-725 K in the sigma(dc)(T) curve, which indicates the existence of a first-order phase transition. The temperature range of the sigma(dc) jump coincides with that of the endothermic effect observed in AgBaSc(VO4)(2) at similar to 723 K. The sigma(dc) value at 835 K is 7 x 10(-5) S/cm. The electrical conductivity mechanism is related to the Ag+ ion transport in the AgBaSc(VO4)(2) lattice.

机译：Agbasc（VO4）（2）含有葡萄矾结构（K3NA（SO 4）（2）型，SP.G1）的钒酸盐晶体的电导率Sigma（DC）已经在5-5×10的频率范围内研究了阻抗光谱法（5）Hz和505至835 K的温度。在Sigma（DC）（T）曲线中，在700-725 k处观察到Sigma（DC）值的跳跃（DC）值与2.5相似的因素，这表明了存在一阶阶段转换。 Sigma（DC）跳跃的温度范围与在Agbasc（VO4）（2）中观察到的吸热效果的温度范围与723K相似。835 K的Sigma（DC）值为7×10（ - 5）S /厘米。电导率机制与Agbasc（VO4）（2）格子中的Ag +离子转运有关。

著录项

来源
《Crystallography reports》 |2019年第1期|共3页
作者
Sorokin N. I.;
展开▼
作者单位

Russian Acad Sci Fed Sci Res Ctr Crystallog &

Photon Shubnikov Inst Crystallog Moscow 119333 Russia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. Ionic Conductivity of AgBaSc(VO4)(2) Crystals with Glaserite-Type Structure [J] . Sorokin N. I. Crystallography reports . 2019,第1期

机译：Agbasc（VO4）（2）晶体与葡萄矾型结构的离子电导率
2. Hydrothermal single-crystal growth in the systems Ag/Hg/X/O (X = V-V,As-V): Crystal structures of (Ag3Hg)VO4, (Ag2Hg2)(3)(VO4)(4) and (Ag2Hg2)(2)(HgO2)(AsO4)(2) with the unusual tetrahedral cluster cations (Ag3Hg)(3+) and (Ag2Hg2)(4+) and crystal str [J] . Weil M, Tillmanns E, Pushcharovsky DY Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第5期

机译：Ag / Hg / X / O（X = VV，As-V）系统中的水热单晶生长：（Ag3Hg）VO4，（Ag2Hg2）（3）（VO4）（4）和（Ag2Hg2）（ 2）（HgO2）（AsO4）（2）具有不常见的四面体簇阳离子（Ag3Hg）（3+）和（Ag2Hg2）（4+）和晶体结构
3. Hydrothermal single-crystal growth in the systems Ag/Hg/X/O (X = V-V,As-V): Crystal structures of (Ag3Hg)VO4, (Ag2Hg2)(3)(VO4)(4) and (Ag2Hg2)(2)(HgO2)(AsO4)(2) with the unusual tetrahedral cluster cations (Ag3Hg)(3+) and (Ag2Hg2)(4+) and crystal str [J] . Weil M, Tillmanns E, Pushcharovsky DY Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第5期

机译：Ag / Hg / X / O（X = VV，As-V）系统中的水热单晶生长：（Ag3Hg）VO4，（Ag2Hg2）（3）（VO4）（4）和（Ag2Hg2）（ 2）（HgO2）（AsO4）（2）具有不常见的四面体簇阳离子（Ag3Hg）（3+）和（Ag2Hg2）（4+）和晶体结构
4. Synthesis, Crystal Structure, and Ionic Conductivity of New Lithium Ion Conductors Based on LaScO_3 with Perovskite Structure [C] . Guowei ZHAO, Iqbal MUHAMMAD, Kola SUZUKI 粉体粉末冶金協会大会 . 2017

机译：基于Lasco_3的新锂离子导体与钙钛矿结构的合成，晶体结构和离子电导率
5. THE EFFECT OF HYDROSTATIC PRESSURE ON THE IONIC CONDUCTIVITY OF SOME CRYSTALS WITH THE FLUORITE STRUCTURE. [D] . OBERSCHMIDT, JAMES MICHAEL. 1980

机译：静水压力对具有萤石结构的某些晶体的离子电导率的影响。
6. The alluaudite-type crystal structures of Na2(Fe/Co)2Co(VO4)3 and Ag2(Fe/Co)2Co(VO4)3 [O] . Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, 2016

机译：Na2（Fe / Co）2Co（VO4）3和Ag2（Fe / Co）2Co（VO4）3的变石型晶体结构
7. The alluaudite-type crystal structures of Na2(Fe/Co)2Co(VO4)3 and Ag2(Fe/Co)2Co(VO4)3 [O] . Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, 2016

机译：Na2（Fe / Co）2Co（VO4）3和ag2（Fe / Co）2Co（VO4）3的铝辉石型晶体结构
8. THE EFFECT OF HYDROSTATIC PRESSURE ON THE IONIC CONDUCTIVITY OF SOME CRYSTALS WITH THE FLUORITE STRUCTURE [R] . JAMES MICHAEL OBSERSCHMIDY 1980

机译：水压对萤石结构某些晶体离子电导率的影响

Ionic Conductivity of AgBaSc(VO4)(2) Crystals with Glaserite-Type Structure

摘要

著录项

相似文献

相关主题

期刊订阅