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Skeletal Sublattices of Heavy Components As a Basis of Stability of Crystal Structures

机译:作为晶体结构稳定性的重型成分的骨骼子分组

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摘要

A crystallographic structural analysis of low- and high-temperature phases of BaSi2O5 and Na3SO4F compounds has been carried out in order to confirm the thesis that the stability of natural-abundant structural types is mainly determined by the configuration of the heaviest components. The geometry of cation (skeletal) sublattices is presented; it is shown that they play a key role in the formation of structures and are relatively stable at temperature phase transitions.
机译:已经进行了Basi2O5和Na 3 SO 4F化合物的低温和高温相的晶体结构分析,以确认自然丰富的结构类型的稳定性主要由最重的组分的配置决定。 介绍了阳离子(骨骼)子晶片的几何形状; 结果表明,它们在形成结构中发挥着关键作用,并且在温度期转变时相对稳定。

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  • 来源
    《Crystallography reports》 |2019年第1期|共6页
  • 作者单位

    Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk 630090 Russia;

    Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk 630090 Russia;

    Russian Acad Sci Nikolaev Inst Inorgan Chem Siberian Branch Novosibirsk 630090 Russia;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
  • 关键词

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