A Novel Coordination Polymer Constructed by Hetero-Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)(2)(mu-H2O)(H2O)(2)](n)

Dou Ming-Yu; Lu Jing

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A Novel Coordination Polymer Constructed by Hetero-Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)(2)(mu-H2O)(H2O)(2)](n)

机译：由杂金属离子和2,3-吡啶二羧酸构成的新型配位聚合物：[NINA2（PDC）（2）（2）（MU-H2O）（H2O）（2））（N）的合成和结构

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A novel coordination polymer containing hetero-metal ions, [NiNa2(PDC)(2)(mu-H2O)(H2O)(2)] (n) , where PDC is 2,3-pyridine dicarboxylate ion, has been synthesized. In the structure, the PDC ligand chelates and bridges two Ni(II) and two Na(I) centers. Two kinds of metal centers are connected by mu(4)-PDC and mu(2)-H2O to form 2D coordination layers. Hydrogen bonds between coordination water molecules and carboxylate oxygen atoms further link these 2D coordination layers to form 3D supramolecular network.

机译：已经合成了含有杂金属离子的新型配位聚合物，[NINA2（PDC）（2）（2）（2）（H 2 O）（2）（2）（2））（N），其中PDC是2,3-吡啶二羧酸二羧酸根离子。在该结构中，PDC配体螯合物和桥两种Ni（II）和两种Na（I）中心。两种金属中心通过MU（4）-PDC和MU（2）-H2O连接，形成2D配位层。协调水分子和羧酸氧原子之间的氢键进一步将这些2D配位层组织形成3D超分子网络。

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来源
《Crystallography reports》 |2017年第7期|共5页
作者
Dou Ming-Yu; Lu Jing;
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作者单位

Liaocheng Univ Shandong Prov Key Lab Chem Energy Storage &

Novel Sch Chem &

Chem Engn Liaocheng 252059 Peoples R China;

Liaocheng Univ Shandong Prov Key Lab Chem Energy Storage &

Novel Sch Chem &

Chem Engn Liaocheng 252059 Peoples R China;

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正文语种 eng
中图分类晶体学;
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1. A Novel Coordination Polymer Constructed by Hetero-Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)(2)(mu-H2O)(H2O)(2)](n) [J] . Dou Ming-Yu, Lu Jing Crystallography reports . 2017,第7期

机译：由杂金属离子和2,3-吡啶二羧酸构成的新型配位聚合物：[NINA2（PDC）（2）（2）（MU-H2O）（H2O）（2））（N）的合成和结构
2. Syntheses, structures, and magnetic properties of two novel cobalt(II) coordination polymers constructed from pyridine-2,6-dicarboxylic acid N-oxide (PDCO) [J] . Wen LL, Tian ZF, Lin JG, Zeitschrift fur Anorganische und Allgemeine Chemie . 2006,第4期

机译：由吡啶-2,6-二羧酸N-氧化物（PDCO）构成的两种新型钴（II）配位聚合物的合成，结构和磁性
3. Metal-Organic Coordination Polymers Containing Pyridine-2,3-dicarboxylic Acid N-Oxide (2,3-PDCO) [J] . Wen LL, Lu ZD, Ren XM, Crystal growth & design . 2009,第1期

机译：包含吡啶-2,3-二羧酸N-氧化物（2,3-PDCO）的金属有机配位聚合物
4. Synthesis, Crystal Structure and Fluorescence Property of Terbium Coordination Polymers with Pyridine-3.5-dicarboxylic Acid [C] . Qisong Shi, Benfeng Hu, Qiuyan Liang, International Conference on Optical, Electronic and Electrical Materials;OEEM2010 . 2011

机译：吡啶-3.5-二羧酸of配合物的合成，晶体结构和荧光性质
5. Electrochemical reformation of levulinic acid and short-chain aliphatic acids and electrochemical polymerization of dicarboxylic acids. [D] . Li, Mingyu. 2016

机译：乙酰丙酸和短链脂肪酸的电化学重整以及二羧酸的电化学聚合。
6. Crystal structure of a novel one-dimensional zigzag chain-like cobalt(II) coordination polymer constructed from 44′-bipyridine and 2-hydroxybenzoate ligands [O] . Thawanrat Saelim, Kittipong Chainok, Filip Kielar, 2020

机译：一种新型一维之曲链链状钴（II）配位聚合物的晶体结构由44-硼烷和2-羟基苯甲酸盐配体构成
7. [Pr2(pdc)3(Hpdc)(H2O)4]n·n(H3hp)·8n(H2O), a One-Dimensional Coordination Polymer Containing PrO6N3 Tri-Capped Trigonal Prisms and PrO8N Mono-Capped Square Anti-Prisms (H2pdc = Pyridine 2,6-Dicarboxylic Acid, C7H5NO4; 3hp = 3-Hydroxy Pyridine, C5H5NO) [O] . Shahzad Sharif, Onur Sahin, Islam Ullah Khan, 2012

机译：[Pr2（pdc）3（Hpdc）（H2O）4] n·n（H3hp）·8n（H2O），一维配位聚合物，其中包含PrO6N3三封三角棱镜和PrO8N单封方形反棱镜（H2pdc =吡啶2,6-二羧酸，C7H5NO4; 3hp = 3-羟基吡啶，C5H5NO）
8. Synthesis of 4- exp 14 C-Pyridine-2,6-Dicarboxylic Acid [R] . Robson, J., Sorby, P. J. 1978

机译：4- exp 14 C-吡啶-2,6-二羧酸的合成

A Novel Coordination Polymer Constructed by Hetero-Metal Ions and 2,3-Pyridine Dicarboxylic Acid: Synthesis and Structure of [NiNa2(PDC)(2)(mu-H2O)(H2O)(2)](n)

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