The First Seven-Coordinated Triiodo Complex of Rhenium(III)

Schoultz X.; Gerber T. I. A.; Betz R.; Hosten E. C.

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The First Seven-Coordinated Triiodo Complex of Rhenium(III)

机译：铼（III）的前七个协调的三碘综合体

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The reaction of cis-[ReO2I(PPh3)(2)] with tert-butyl isocyanide in benzene led to the isolation of the complex [ReI3(CN-t-Bu)(3)(PPh3)] (1). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.

机译：CIS-[REO2I（PPH3）（2）]在苯中与叔丁基异氰酸酯的反应导致复合物[REI3（CN-T-BU）（3）（PPH3）]（1）的分离。复杂的是异常的，因为它含有大锥角的庞大配体，即三种碘化物，三种异氰酸酯，具有叔丁基的三种异氰酸酯，作为铼（III）金属离子的七坐标几何形状中的配体。

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《Crystallography reports》 |2017年第7期|共3页
作者
Schoultz X.; Gerber T. I. A.; Betz R.; Hosten E. C.;
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Nelson Mandela Metropolitan Univ Dept Chem Port Elizabeth South Africa;

Nelson Mandela Metropolitan Univ Dept Chem Port Elizabeth South Africa;

Nelson Mandela Metropolitan Univ Dept Chem Port Elizabeth South Africa;

Nelson Mandela Metropolitan Univ Dept Chem Port Elizabeth South Africa;

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中图分类晶体学;
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1. The First Seven-Coordinated Triiodo Complex of Rhenium(III) [J] . Schoultz X., Gerber T. I. A., Betz R., Crystallography reports . 2017,第7期

机译：铼（III）的前七个协调的三碘综合体
2. SYNTHESIS AND CHARACTERIZATION OF RHENIUM(III) AND TECHNETIUM(III) ORGANOHYDRAZIDE CHELATE COMPLEXES - REACTIONS OF 2-HYDRAZINOPYRIDINE WITH COMPLEXES OF RHENIUM AND TECHNETIUM [J] . Hirschkuchma M., Davison A., Davis WM., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第15期

机译：GAN（）和（III）有机OR螯合物的合成与表征-2-H代吡啶与HEN和COMP的络合物的反应
3. Studies of V(III) complexes with selected alpha-N-heterocyclic carboxylato NO donor ligands: structure of a new seven-coordinated pentagonal bipyramidal complex containing picolinato ligands [J] . Chatterjee M., Ghosh S., Mak TCW., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第21期

机译：具有选定的α-N-杂环羧基羧基NO供体配体的V（III）配合物的研究：含picolinato配体的新型七配位五边形双锥体络合物的结构
4. Rhenium-Catalyzed Activation of Olefinic C-H Bond: Synthesis of Cyclopentadienyl-Rhenium Complexes [C] . Takashi Matsuki, Yuta Nishina, Yoichiro Kuninobu Symposium on Organometallic Chemistry . 2008

机译：铼催化烯烃C-H键的活化：环戊二烯基 - 铼络合物的合成
5. I. Synthesis, reactivity, and structural studies of rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands. II. Synthesis and reactivity of novel rhenium methylidene complexes. [D] . Krumper, Jennifer. 2003

机译：I.新型双（恶唑啉）夹钳配体的铑（III）和铑（II）配合物的合成，反应性和结构研究。二。新型methyl亚甲基配合物的合成和反应性。
6. Rhenium(I) Carbonyl Complexes of 246-Tris(2-pyridyl)-135-triazine (TPT). Rhenium(I)-Promoted Methoxylation of the Triazine Ring Carbon Atom in Dinuclear Rhenium Complexes [O] . Xiaoyuan Chen, Frank J. Femia, John W. Babich, -1

机译：246-三（2-吡啶基）-135-三嗪（TPT）的Carbon（I）羰基配合物。 nu（I）促进双核R配合物中三嗪环碳原子的甲氧基化
7. Studies of β-diketone complexes of rhenium. IX. The preparation and characterization of salts of the trans-dihalobis(pentane-2,4-dionato)rhenate(III) anion and an improved preparation of tris(pentane-2,4-dionato)rhenium(III) [O] . C. J. L. Lock, C. N. Murphy, M. L. Turner 1979

机译：铼β-Diketone复合物的研究。 IX。反式二卤石（戊烷-2,4-二乙基）renate（III）阴离子的制备和表征和改进的Tris（戊烷-2,4-二乙酯）铼（III）的制剂
8. Synthesis of 'Skewered Complexes':Reaction of Rhenium Carbonyl Porphyrin Complexes with Antimony Pentachloride. [R] . kato, s. tsutsui, minoru 1976

机译：“串联配合物”的合成：铼羰基卟啉配合物与五氯化锑的反应。

The First Seven-Coordinated Triiodo Complex of Rhenium(III)

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