Synthesis and Crystal Structure of Di-mu-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-kappa N)aniline-kappa N]mercury(II)}

Khalaj M.; Seftejani F. B.; Ghazanfarpour-Darjani M.; Lalegani A.

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Synthesis and Crystal Structure of Di-mu-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-kappa N)aniline-kappa N]mercury(II)}

机译：Di-Mu-Hollido-BIS（氯通[4-乙基-N-（吡啶-2-萘甲基-Kappa n）苯胺-Kappa n]汞（ii）}的合成与晶体结构。

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The centrosymmetric dinuclear title complex [Hg2Cl4(dip)(2)] was synthesized using the Schiff base bidentate ligand (E)-4-ethyl-N-(pyridine-2-ylmethylene) benzeneamine (dip) and mercury(II) chloride salts. It has been characterized by elemental analysis, X-ray diffraction, and UV-Visible and infrared spectroscopic techniques. The X-ray analysis shows that the title compound crystallizes in the monoclinic sp. gr. P2(1)/n, Z = 2 with a = 7.8233(17)angstrom, b = 15.178(3)angstrom, c = 12.559(3)angstrom, beta= 97.021(3)degrees. The Hg(II) ion has a distorted trigonal-bipyramidal coordination environment formed by the bischelating N-heterocyclic ligands, two bridging Cl atoms and one terminal Cl atom.

机译：使用Schiff碱二齿配体（E）-4-乙基-N-（吡啶-2-基甲基）苯并氨基（浸渍）和汞（II）氯化物盐合成了CentroSymmetric二核标题复合物[Hg2Cl4（浸渍）（2）] 。它的特征在于元素分析，X射线衍射和UV可见光和红外光谱技术。 X射线分析表明标题化合物在单斜晶型中结晶。 GR。 P2（1）/ N，Z = 2，A = 7.8233（17），B = 15.178（3）埃，C = 12.559（3）埃，β= 97.021（3）度。 HG（II）离子具有由双晶的N-杂环配体，两个桥接CL原子和一个末端CL原子形成的扭曲的三角形 - 双脉络绿区间配位环境。

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来源
《Crystallography reports》 |2017年第7期|共3页
作者
Khalaj M.; Seftejani F. B.; Ghazanfarpour-Darjani M.; Lalegani A.;
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作者单位

Islamic Azad Univ Buinzahra Branch Young Researchers &

Elite Club Buinzahra Iran;

Islamic Azad Univ Buinzahra Branch Young Researchers &

Elite Club Buinzahra Iran;

Islamic Azad Univ Buinzahra Branch Young Researchers &

Elite Club Buinzahra Iran;

Islamic Azad Univ Buinzahra Branch Young Researchers &

Elite Club Buinzahra Iran;

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正文语种 eng
中图分类晶体学;
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Synthesis and Crystal Structure of Di-mu-chlorido-bis{chlorido[4-ethyl-N-(pyridin-2-ylmethylidene-kappa N)aniline-kappa N]mercury(II)}

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