Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(alpha-pyridyl)bispidone Moiety

Polyakova I. N.; Sokol V. I; Sergienko V. S.; Kolyadina N. M.; Kvartalov V. B.; Polyanskaya N. A.

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Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(alpha-pyridyl)bispidone Moiety

机译：镍（II）复合物的晶体结构与含有嵌入式二（α-吡啶基）双戊酮部分的大环氮杂苯并苯并-14-冠4醚配体

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The crystal structure of the nickel(II) complex with substituted azadibenzo-14-crown-4 ether containing the embedded di(alpha-pyridyl)bispidone moiety having the formula [Z(H2O)Ni(NO3) Ni(H2O)L](ClO4)(3) . 0.7EtOH was studied by X-ray diffraction (T = 150(2) K, R = 0.0628). In the complex cation two five-coordinate nickel complexes are bridged by the nitrate anion to form a dimer. The distorted octahedral environment of Ni atoms is formed by four nitrogen atoms of the molecule L and the oxygen atoms of the water molecule and the NO3- anion. In the nickel complex, like in the cobalt and copper complexes studied previously, the bispidine moiety of the molecule L adopts a chair-chair conformation.

机译：镍（II）络合物的晶体结构与具有式[Z（H2O）Ni（NO 3）Ni（H 2 O）Ni（H 2 O）Ni（NO 3）Ni（NO 3）Ni（H 2 O）L]（ CLO4）（3）。通过X射线衍射研究0.7℃（T = 150（2）K，R = 0.0628）。在复杂的阳离子中，两个五坐标镍络合物通过硝酸根阴离子桥接以形成二聚体。 Ni原子的扭曲的八面体环境由分子L的四个氮原子和水分子的氧原子和NO3-阴离子形成。在镍络合物中，如前研究过的钴和铜络合物中，分子L的Bispidine部分采用椅子椅子构象。

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《Crystallography reports》 |2018年第3期|共6页
作者
Polyakova I. N.; Sokol V. I; Sergienko V. S.; Kolyadina N. M.; Kvartalov V. B.; Polyanskaya N. A.;
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Russian Acad Sci Kurnakov Inst Gen &

Inorgan Chem Moscow 119991 Russia;

Russian Acad Sci Kurnakov Inst Gen &

Inorgan Chem Moscow 119991 Russia;

Russian Acad Sci Kurnakov Inst Gen &

Inorgan Chem Moscow 119991 Russia;

Peoples Friendship Univ Russia Moscow 117198 Russia;

Natl Res Ctr Kurchatov Inst Moscow 123098 Russia;

Peoples Friendship Univ Russia Moscow 117198 Russia;

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中图分类晶体学;
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1. Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(alpha-pyridyl)bispidone Moiety [J] . Polyakova I. N., Sokol V. I, Sergienko V. S., Crystallography reports . 2018,第3期

机译：镍（II）复合物的晶体结构与含有嵌入式二（α-吡啶基）双戊酮部分的大环氮杂苯并苯并-14-冠4醚配体
2. MAGNETIC PROPERTIES OF BINUCLEAR MANGANESE(II), COBALT(II), NICKEL(II) AND COPPER(II) COMPLEXES OF A MACROCYCLIC LIGAND DERIVED FROM PYRIDINE-N-OXIDE, AND CRYSTAL STRUCTURE OF THE NICKEL COMPLEX [J] . Blake AB., Yavari A., Moubaraki B., Inorganica Chimica Acta . 1995,第1a2期

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3. Formation and dissociation kinetics and crystal structures of nickel(II)-macrocyclic tetrathiaether complexes in acetonitrile. Comparison to nickel(II)-macrocyclic tetramines [J] . Kulatilleke CP., Heeg MJ., Ochrymowycz LA., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000,第7期

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4. Synthesis of novel dinuclear cobalt complexes of 2+2 macrocyclic ligands with a bis(imino)pyridine moiety [C] . Yoshinori Shibata, Toshi Nagata 日本化学会春季年会講演予稿集 . 2018

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6. Crystal structures of two nickel(II) macrocyclic salts: (577121214-hexamethyl-14811-tetraazacyclotetradecane)nickel(II) bis(perchlorate) monohydrate and (577121214-hexamethyl-14811-tetraazacyclotetradecane)nickel(II) dibromide trihydrate [O] . Peter W. R. Corfield, Virgil L. Goedken 2019

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7. Solid-State Structures and Magnetic Properties of Halide-Bridged, Face-to-Face Bis-Nickel(II)-Macrocyclic Ligand Complexes: Ligand-Mediated Interchanges of Electronic Configuration [O] . -1

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8. Dinuclear Complexes of a (30)Py2N4O4 Macrocyclic Ligand Containing Two Alpha, Alpha'-Bis(aminomethyl)pyridine Moieties. Comparison with Analogous 22- and 24-Membered Macrocyclic Ligands. [R] . Menif, R., Chen, D., Martell, A. E. 1989

机译：含有两个α，α'-双（氨基甲基）吡啶部分的（30）py2N4O4大环配体的双核配合物。与类似的22和24元大环配体的比较。

Crystal Structure of a Nickel(II) Complex with the Macrocyclic Azadibenzo-14-crown-4 Ether Ligand Containing the Embedded Di(alpha-pyridyl)bispidone Moiety

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