Synthesis, Structure, and Band Gap of a Novel InorganicOrganic Hybrid Material Based on Antimony Halide and Organoamine

Long Ji-Ying; Yan Zhi-Shuo; Gong Yun

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Synthesis, Structure, and Band Gap of a Novel InorganicOrganic Hybrid Material Based on Antimony Halide and Organoamine

机译：基于锑卤化物和有机胺的新型无机杂化材料的合成，结构和带隙

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Using an organoamine, 2,5-bis (1-imidazoly) pyridine (L), a novel inorganic-organic hybrid material based on antimony halide formulated as {(CH3)(2)L}(2+){(Sb4Cl8I8)(0.5)}(2-) (1) was synthesized in situ via solvothermal technique and characterized by the single-crystal X-ray diffraction. During the synthesis, the organoamine L was transformed in situ into the imidazolium ion, {(CH3)(2)L}(2+). In the compound 1, four Sb(III) ions are linked by two u(3)-I- and four u(2)-I- ligands into a (Sb4I8Cl8)(4-) unit, in which eight Cl- ions and two I- ions act as the terminal ligands. The uncoordinated {(CH3)(2)L}(2+) organoamine moieties are linked with the (Sb4I8Cl8)(4-) clusters via H bonds into three-dimensional (3D) supramolecular architecture. The band structure calculation shows that the compound has an indirect band gap of 2.253 eV.

机译：使用有机胺，2,5-双（1-咪唑）吡啶（L），一种基于配制为（（CH3）（2）L}（2 +）（SB4Cl8i8）（SB4Cl8i8）（SB4Cl8I8）（SB4Cl8i8）（ 0.5）}（2-）（1）原位通过溶剂热技术合成，并通过单晶X射线衍射特征。在合成期间，将有机胺L原位转化到咪唑鎓离子中，{（CH 3）（2）L}（2+）。在化合物1中，将四个Sb（III）离子由两个U（3）-i-和四个U（2）-i-配体连接成（Sb4i8Cl8）（4-）单位，其中八个链条和两种IIENS作为终端配体。未配备的{（CH3）（2）L}（2+）有机胺部分与通过H键合成三维（3D）超分子结构的（Sb4i8Cl8）（4-）簇。带结构计算表明该化合物具有2.253eV的间接带隙。

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《Crystallography reports》 |2018年第3期|共5页
作者
Long Ji-Ying; Yan Zhi-Shuo; Gong Yun;
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Chongqing Univ Coll Chem &

Chem Engn Dept Appl Chem Chongqing 401311 Peoples R China;

Chongqing Univ Coll Chem &

Chem Engn Dept Appl Chem Chongqing 401311 Peoples R China;

Chongqing Univ Coll Chem &

Chem Engn Dept Appl Chem Chongqing 401311 Peoples R China;

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中图分类晶体学;
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2. Two Heteromorphic Crystals of Antimony-Based Hybrids Showing Tunable Optical Band Gaps and Distinct Photoelectric Responses [J] . Li Yaobin, Xu Zhiyun, Liu Xitao, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第9期

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Synthesis, Structure, and Band Gap of a Novel InorganicOrganic Hybrid Material Based on Antimony Halide and Organoamine

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