Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands

J. N. Xing; J. Z. Guo; B. Li

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Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands

机译：从苯并偶联-2,4'-二羧酸甲酯和1,4-双（1H-咪唑-1-基）丁烷混合配体产生的三维CD（II）配位聚合物的合成，晶体结构和发光

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A new coordination polymer, namely, [Cd(L)(BIB)~(0.5)]~( n )(H~(2) L = benzophenone-2,4′-dicarboxylic acid, BIB = 1,4-bis(1H-imidazol-1-yl)butane), was synthesized under hydrothermal condition. Single-crystal X-ray analysis reveals that two adjacent Cd(II) ions are bridged by four L _(2?)ligands to form a two-dimensional layers, which are further connected by BIB to build a beautiful three-dimensional (3D) network. The luminescent and thermal properties of the compound are investigated.

机译：一种新的配位聚合物，即[Cd（L）（围兜）〜（0.5）]〜（n）（H〜（2）L =二苯甲酮-2,4'-二羧酸，围绕= 1,4-双（ 1H-咪唑-1-基）丁烷），在水热条件下合成。单晶X射线分析显示，两个相邻的CD（II）离子桥接四个L _（2？）配体以形成二维层，其通过围兜进一步连接以构建美丽的三维（3D ）网络。研究了化合物的发光和热性质。

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《Crystallography reports》 |2018年第4期|共4页
作者
J. N. Xing; J. Z. Guo; B. Li;
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Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass Zhejiang A and F University;

Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass Zhejiang A and F University;

Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass Zhejiang A and F University;

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Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands

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