Synthesis and characterization of new open-framework vanadium tellurite featuring an unprecedented (3,7)-connected network: K_3[(V ~VO_4)(V~(IV)O)_4(TeO_3) _4]?4H_2O

Huang X.-H.; Huang C.-C.; Liu D.-S.; Liu Z.-Q.; Wang Y.-B.

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Synthesis and characterization of new open-framework vanadium tellurite featuring an unprecedented (3,7)-connected network: K_3[(V ~VO_4)(V~(IV)O)_4(TeO_3) _4]?4H_2O

机译：具有空前的（3,7）连接网络的新型开放式骨架钒碲石的合成与表征：K_3 [（V〜VO_4）（V〜（IV）O）_4（TeO_3）_4]？4H_2O

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Hydrothermal reaction of TeO_2, V_2O_5, K_2C_2O_4, H_2C_2O_4 in water yielded a novel vanadium tellurite, K_3[(V~VO _4)(V~(IV)O)_4(TeO_3)_4] ?4H_2O. The compound exhibits 2 [V_4Te _4O_(18)]~(4-) puckered anionic layers that are pillared by [VO_4]~(3-) units into a three-dimensional inorganic open framework with unprecedented (3,7)-connected (4~3) _2(4~6?6~(10)?8~5) topology.

机译：TeO_2，V_2O_5，K_2C_2O_4，H_2C_2O_4在水中的水热反应产生了一种新型钒碲石，K_3 [（V〜VO _4）（V〜（IV）O）_4（TeO_3）_4]？4H_2O。该化合物具有2个[V_4Te _4O_（18）]〜（4-）褶皱的阴离子层，这些层由[VO_4]〜（3-）单元柱撑成具有前所未有的（3,7）连接的三维无机开放骨架（ 4〜3）_2（4〜6？6〜（10）？8〜5）拓扑。

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《Crystal growth & design》 |2010年第5期|共4页
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Huang X.-H.; Huang C.-C.; Liu D.-S.; Liu Z.-Q.; Wang Y.-B.;
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1. Synthesis and characterization of new open-framework vanadium tellurite featuring an unprecedented (3,7)-connected network: K_3[(V ~VO_4)(V~(IV)O)_4(TeO_3) _4]?4H_2O [J] . Huang X.-H., Huang C.-C., Liu D.-S., Crystal growth & design . 2010,第5期

机译：具有空前的（3,7）连接网络的新型开放式骨架钒碲石的合成与表征：K_3 [（V〜VO_4）（V〜（IV）O）_4（TeO_3）_4]？4H_2O
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Synthesis and characterization of new open-framework vanadium tellurite featuring an unprecedented (3,7)-connected network: K_3[(V ~VO_4)(V~(IV)O)_4(TeO_3) _4]?4H_2O

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