Crystallization in unsaturated glycine/D_2O solution achieved by irradiating a focused continuous wave near infrared laser

Rungsimanon T.; Yuyama K.-I.; Sugiyama T.; Masuhara H.

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Crystallization in unsaturated glycine/D_2O solution achieved by irradiating a focused continuous wave near infrared laser

机译：通过照射聚焦连续波近红外激光在不饱和甘氨酸/ D_2O溶液中结晶

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The crystallization of glycine in unsaturated solution is made possible by laser trapping of its molecular clusters due to photon pressure of a focused continuous wave near-infrared laser beam. Always one single crystal is spatiotemporally formed at a focal spot, and then it undergoes dissolution, eventually leading to repetitive crystallization and dissolution. The polymorph characterization of the crystal formed in unsaturated solution confirmed the γ-form, which is not obtainable by conventional crystallization methods. The preparation probability of the γ-form compared to the α-form is much higher than that in the supersaturated solution.

机译：由于聚焦连续波近红外激光束的光子压力，甘氨酸在不饱和溶液中的结晶可以通过激光捕获其分子簇而实现。通常在焦点上时空形成一个单晶，然后进行溶解，最终导致重复结晶和溶解。在不饱和溶液中形成的晶体的多晶型特征证实了γ-形式，这是常规结晶方法无法获得的。与α-形式相比，γ-形式的制备可能性远高于过饱和溶液中的制备可能性。

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《Crystal growth & design》 |2010年第11期|共3页
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Rungsimanon T.; Yuyama K.-I.; Sugiyama T.; Masuhara H.;
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1. Crystallization in unsaturated glycine/D_2O solution achieved by irradiating a focused continuous wave near infrared laser [J] . Rungsimanon T., Yuyama K.-I., Sugiyama T., Crystal growth & design . 2010,第11期

机译：通过照射聚焦连续波近红外激光在不饱和甘氨酸/ D_2O溶液中结晶
2. World's First Crystallization of Glycine Only by Continuous-wave Laser [J] . Japan Chemical Week Group Japan Chemical Week . 2007,第2439期

机译：仅通过连续波激光，世界上第一个甘氨酸结晶
3. Non-Photochemical Pulsed-Laser-Induced Nucleation in a Continuous-Wave-Laser-Induced Phase-Separated Solution Droplet of Aqueous Glycine Formed by Optical Gradient Forces [J] . Gowayed Omar, Tasnim Tasfia, Fuentes-Rivera Jose J., Crystal growth & design . 2019,第12期

机译：通过光学梯度力形成的连续波激光诱导的连续波激光诱导的相分离溶液液体的非光化学脉冲激光诱导的核切割
4. High Efficiency Crystallization of Silicon Thin Films Using Continuous Wave Infrared Laser [C] . Naoki Sano, Masato Maki, Nobuyuki Andoh, Materials Research Society Symposium on Amorphous and Polycrystalline Thin-Film Silicon Science and Technology . 2007

机译：使用连续波红外激光器的硅薄膜高效率结晶
5. Effect of continuous wave laser irradiation on structural relaxation and mechanical properties of Iron-Silicon-Boron amorphous ribbon. [D] . Haque, Md Farhadul. 2013

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7. Spectral Superbroadening of Self-Focused Picosecond Laser Pulses in D_2O [O] . Penzkofer Alfons, Beidoun A., Lehmeier H. 1993

机译：D_2O中自聚焦皮秒激光脉冲的光谱超宽化

Crystallization in unsaturated glycine/D_2O solution achieved by irradiating a focused continuous wave near infrared laser

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