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首页> 外文期刊>Crystal growth & design >Topotactic changes in thin films of brownmillerite SrFeO_(2.5) grown on SrTiO_3 substrates to infinite-layer structure SrFeO _2
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Topotactic changes in thin films of brownmillerite SrFeO_(2.5) grown on SrTiO_3 substrates to infinite-layer structure SrFeO _2

机译:在SrTiO_3衬底上生长的棕褐色SrFeO_(2.5)薄膜的无规层结构SrFeO _2的全向性变化

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摘要

A brownmillerite SrFeO_(2.5) thin film grown on a SrTiO _3(001) substrate contained an a-axis-oriented single-crystalline domain near the substrate and multiple domains with three orthogonal orientations. When the film was reduced with CaH_2, it changed topotactically to a homogeneous c-axis-oriented infinite-layer structure, SrFeO_2. A brownmillerite SrFeO_(2.5) thin film grown on a SrTiO_3(111) substrate and treated with CaH_2 at 250 °C also changed to (111)-oriented SrFeO_2 with an infinite-layer structure. During reduction at low temperatures, the framework of the perovskite-structure stays intact, some oxygen atoms are removed from it, and others are rearranged.
机译:在SrTiO _3(001)衬底上生长的棕褐色SrFeO_(2.5)薄膜包含靠近衬底的a轴取向单晶畴和具有三个正交方向的多个畴。当用CaH_2还原膜时,它实际上变成了均匀的c轴取向无限层结构SrFeO_2。在SrTiO_3(111)衬底上生长并在250°C下用CaH_2处理的棕褐色SrFeO_(2.5)薄膜也变为具有无限层结构的(111)取向的SrFeO_2。在低温下还原过程中,钙钛矿结构的框架保持完整,一些氧原子从其中除去,另一些重新排列。

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