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Ionothermal synthesis of BiOCl Nanostructures via a long-chain ionic liquid precursor route

机译:通过长链离子液体前体路线离子热合成BiOCl纳米结构

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摘要

Ultrathin BiOCl nanoflakes, nanoplate arrays, and curved nanoplates have been successfully synthesized via an ionothermal synthetic route by using an ionic liquid 1-hexadecyl-3-methylimidazolium chloride ([C_(16)Mim]Cl) as "all-in-one" solvent, simply adjusting reaction temperature. The samples are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM) and Fourier transform infrared spectroscopy (FT-IR), separately. Possible formation mechanisms of various nanostructures were proposed in terms of crystal growth habit and dynamics. In addition, the excellent adsorption performance of the as-prepared BiOCl nanoplates makes them useful with potential applications in the aspect of wastewater treatment.
机译:通过使用离子液体1-十六烷基-3-甲基咪唑鎓氯化物([C_(16)Mim] Cl)作为“多合一”化合物,通过电热合成途径成功合成了超薄BiOCl纳米薄片,纳米板阵列和弯曲的纳米板。溶剂,只需调节反应温度即可。分别通过X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM),高分辨率透射电子显微镜(HR-TEM)和傅立叶变换红外光谱(FT-IR)对样品进行表征。根据晶体的生长习性和动力学,提出了各种纳米结构的可能形成机理。另外,所制备的BiOCl纳米板的优异吸附性能使其在废水处理方面具有潜在的应用价值。

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