Three Metal-Organic Frameworks Based on Binodal Inorganic Building Units and Hetero-O, N Donor Ligand: Solvothermal Syntheses, Structures, and Gas Sorption Properties

Luo Xiaolong; Sun Libo; Zhao Jun; Li Dong-Sheng; Wang Dongmei; Li Guanghua; Huo Qisheng; Liu Yunling

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Three Metal-Organic Frameworks Based on Binodal Inorganic Building Units and Hetero-O, N Donor Ligand: Solvothermal Syntheses, Structures, and Gas Sorption Properties

机译：基于双歧杆菌无机建筑单元和杂O，N供体配体的三种金属有机骨架：溶剂热合成，结构和气体吸附特性

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Three new metal organic frameworks (MOFs) based on hetero-O, N donor ligands, (Cu4I4) [Cu-2(PDC)(2)-DMF2](2)center dot 2DMF center dot H2O (JLU-Liu15), (Cu4I4)[Cu-3(CPNA)(3)(Dabco)(0.5)DMF3]center dot 4DMF center dot 4H(2)O (JLU-Liu16), and (Cu4I4)-[Cu-3(CPNA)(3)(H2O)(0.5)DMF3]center dot 4DMF.4H(2)O (JLU-Liu17), (H2PDC = pyridine-3,5-dicarboxylic acid, H(2)CPNA = (5-(4'-carboxylphenyl) nicotinic acid, Dabco = 1,4-diazabicyclo[2.2.2]octane), have been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction analyses. JLU-Liu15 features a (3,4,4)-c sqc5588 net, whereas JLU-Liu16 and JLU-Liu17 are isostructural and possess a new (3,4,4)-c topology. All of these compounds are composed of the binodal inorganic Cu-2(CO2)(4) paddlewheel and Cu4I4 cluster secondary building units (SBUs). It is worthy to note that the linkage between two nearby Cu4I4 clusters in JLU-Liu16 is mu(2)-Dabco, which changed to a mu(2)-water molecule in JLU-Liu17. Furthermore, JLU-Liu15 exhibits high CO2 adsorption behaviors as well as I-2 uptake and release features.

机译：三种基于杂-O，N供体配体（Cu4I4）[Cu-2（PDC）（2）-DMF2]（2）中心点2DMF中心点H2O（JLU-Liu15）的新型金属有机骨架（MOF），（ Cu4I4）[Cu-3（CPNA）（3）（Dabco）（0.5）DMF3]中心点4DMF中心点4H（2）O（JLU-Liu16）和（Cu4I4）-[Cu-3（CPNA）（3 ）（H2O）（0.5）DMF3]中心点4DMF.4H（2）O（JLU-Liu17），（H2PDC =吡啶-3,5-二羧酸，H（2）CPNA =（5-（4'-羧基苯基））烟酸，Dabco = 1,4-二氮杂双环[2.2.2]辛烷）已经溶剂热合成并通过单晶X射线衍射分析对其结构进行了表征，JLU-Liu15的特征是（3,4,4）-c sqc5588网，而JLU-Liu16和JLU-Liu17是同构结构，并具有新的（3,4,4）-c拓扑结构，所有这些化合物均由双链无机Cu-2（CO2）（4）桨轮和Cu4I4值得注意的是，JLU-Liu16中两个附近的Cu4I4簇之间的联系是mu（2）-Dabco，在JLU-Liu17中变成了mu（2）-水分子。，JLU- Liu15具有较高的CO2吸附性能以及I-2吸收和释放特性。

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《Crystal growth & design》 |2015年第10期|共7页
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Luo Xiaolong; Sun Libo; Zhao Jun; Li Dong-Sheng; Wang Dongmei; Li Guanghua; Huo Qisheng; Liu Yunling;
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机译：基于双歧杆菌无机建筑单元和杂O，N供体配体的三种金属有机骨架：溶剂热合成，结构和气体吸附特性
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Three Metal-Organic Frameworks Based on Binodal Inorganic Building Units and Hetero-O, N Donor Ligand: Solvothermal Syntheses, Structures, and Gas Sorption Properties

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