...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Crystal growth & design >Cesium Cyano-Bridged Co~(II)?M~V (M = Mo and W) Layered Frameworks Exhibiting High Thermal Durability and Metamagnetism
【24h】

Cesium Cyano-Bridged Co~(II)?M~V (M = Mo and W) Layered Frameworks Exhibiting High Thermal Durability and Metamagnetism

机译：铯铯桥接Co〜（II）？M〜V（M = Mo和W）层状骨架，具有较高的热耐久性和超磁性

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Two-dimensional cesium bimetal cyano-bridged assemblies Cs_4~ICo~(II)[Mo~V(CN)_8]Cl_3 (CsCoMo) and Cs_4~ICo~(II)[W~V(CN)_8]Cl_3 (CsCoW) were synthesized. The negatively charged and solvent-free {Co~(II)[M~V(CN)_8]Cl_3}~(4?) (M = Mo, W) coordination layers are separated by Cs~+ ions. Themogravimetric measurements show that these compounds reveal high thermal durability up to 523 K (250 °C), which is due to the absence of solvent molecules in their crystal structures. The magnetic measurements show that CsCoMo and CsCoW are metamagnets showing the field-induced transition from an antiferromagnetic phase with Ne?el temperature of 25 K to a ferromagnetic phase, which is observed at high critical magnetic field of 24 kOe at 1.8 K. These originate from antiferromagnetic interactions between ferromagnetically coupled cyano-bridged Co~(II)?M~V layers, and the contribution from single-ion anisotropy of Co~(II).
机译：二维铯双金属氰基桥组装体Cs_4〜ICo〜（II）[Mo〜V（CN）_8] Cl_3（CsCoMo）和Cs_4〜ICo〜（II）[W〜V（CN）_8] Cl_3（CsCoW）被合成。带有负电荷且无溶剂的{Co〜（II）[M〜V（CN）_8] Cl_3}〜（4？）（M = Mo，W）配位层被Cs〜+离子隔开。重量分析表明，这些化合物显示出高达523 K（250°C）的高热耐久性，这是由于其晶体结构中不存在溶剂分子。磁测量表明，CsCoMo和CsCoW是超磁体，显示出从磁场温度25 K的反铁磁相到铁磁相的场感应跃迁，在1.8 k的24 kOe高临界磁场中观察到。铁磁耦合的氰基桥联Co〜（II）？M〜V层之间的反铁磁相互作用，以及Co〜（II）的单离子各向异性的贡献。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号