A Microporous Metal?Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation

Hussah Alawisi; Bin Li; Yabing He; Hadi D. Arman; Abdullah M. Asiri; Banglin Chen; Hailong Wang

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A Microporous Metal?Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation

机译：一种由新型四羧酸构造的微孔金属有机骨架，用于选择性气体分离

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A new organic ligand of pyrene-containing tetracarboxylic acid and its first metal?organic framework UTSA-72 was designed and synthesized. The MOF has the two-dimensional (4,4) framework topology. The activated UTSA-72a exhibits permanent porosity and moderately high selectivities for CO_2/N_2, C_2H_2/CH_4, and CO_2/CH_4 gas separations at room temperature because of the small pores within the framework.

机译：设计并合成了一种新的含pyr四羧酸有机配体及其第一个金属有机骨架UTSA-72。 MOF具有二维（4,4）框架拓扑。活化的UTSA-72a在室温下表现出永久的孔隙率和对CO_2 / N_2，C_2H_2 / CH_4和CO_2 / CH_4气体分离的适度高的选择性，这是因为骨架内的孔很小。

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来源
《Crystal growth & design》 |2014年第5期|共5页
作者
Hussah Alawisi; Bin Li; Yabing He; Hadi D. Arman; Abdullah M. Asiri; Banglin Chen; Hailong Wang;
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正文语种 eng
中图分类晶体学;
关键词
framework; porosity; separations;

机译：框架;孔隙度;分离;

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专利

1. A Microporous Metal?Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation [J] . Hussah Alawisi, Bin Li, Yabing He, Crystal growth & design . 2014,第5期

机译：一种由新型四羧酸构造的微孔金属有机骨架，用于选择性气体分离
2. A copper-based metal-organic framework constructed from a new tetracarboxylic acid for selective gas separation [J] . Dan Yan, Banglin Chen, Qian Duan Inorganic Chemistry Communications . 2014,第Null期

机译：由新的四羧酸构造的铜基金属有机骨架，用于选择性气体分离
3. Microporous Lanthanide Metal-Organic Framework Constructed from Lanthanide Metalloligand for Selective Separation of C2H2/CO2 and C2H2/CH4 at Room Temperature [J] . Ma Jing-xin, Guo Jiarui, Wang Hailong, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2017,第12期

机译：由镧系金属金属 - 有机骨架构成的微孔镧系有机框架，用于在室温下选择性分离C 2 H 2 / CO 2和C 2 H 2 / CH 4
4. A MICROPOROUS HYDROGEN-BONDED ORGANIC FRAMEWORK FOR HIGHLY SELECTIVE C2H2/C2H4 SEPARATION AT AMBIENT TEMPERATURE [C] . Peng Li, Banglin Chen ACS National Meeting and Exhibition . 2014

机译：用于在环境温度下的高选择性C 2 H 2 / C 2 H 4分离的微孔氢键有机骨架
5. Functionalization of 1,6,7,12-Tetrachloroperylene Tetracarboxylic Acid Anhydride for Synthesis of Metal-Organic Frameworks in Energy Applications [D] . ?Palukoshka, Andrei 2020

机译：1,6,7,12-四氯化氢萘甲酸酐在能量应用中合成金属 - 有机框架的官能化
6. A 2D Metal-Organic Framework with a Flexible Cyclohexane-1256-tetracarboxylic Acid Ligand: Synthesis Characterization and Photoluminescent Property [O] . Rongming Wang, Jian Zhang, Lijuan Li -1

机译：具有柔性环己烷-1256-四羧酸配体的2D金属 - 有机骨架：合成表征和光致发光性
7. A microporous metal-organic framework with rare lvt topology for highly selective C2H2/C2H4 separation at room temperature [O] . Wen, H.M., Li, B., Wang, H., 2015

机译：具有罕见lvt拓扑结构的微孔金属有机框架，可在室温下高度选择性地分离C2H2 / C2H4

A Microporous Metal?Organic Framework Constructed from a New Tetracarboxylic Acid for Selective Gas Separation

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