One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System

Boege Matthias; Heck Juergen

首页> 外文期刊>Crystal growth & design >One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System

【24h】

One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System

机译：从两相溶剂体系一步制备几乎不溶的钯（II）和铂（II / IV）配合物并进行结晶

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Scarcely soluble palladium(II) and platinum(II/IV) halido complexes with diamino ligands were prepared via a biphasic solvent system. Metal precursors like tetrachloridopalladate salts were dissolved in oxygen-free water, whereas the organic cliamino ligands were dissolved in dry and oxygen-free dichloromethane. The dichloromethane layer was carefully covered with the aqueous layer under nitrogen atmosphere at room temperature. The desired products crystallized within a few weeks at the phase boundary. In the case of dihalidopalladium complexes with diamino-binaphthalene and diamino-carbohydrate ligands, crystals were obtained without further manipulation that were suitable for X-ray structure analysis.

机译：通过双相溶剂系统制备了难溶的具有二氨基配体的钯（II）和铂（II / IV）卤化物配合物。将金属前体（如四氯化钯）盐溶解在无氧水中，而将有机cliamino配体溶解在干燥且无氧的二氯甲烷中。在室温和氮气气氛下，用水层小心地覆盖二氯甲烷层。所需产物在数周内在相边界处结晶。在具有二氨基联萘和二氨基碳水化合物配体的二卤代钯络合物的情况下，无需进一步操作即可获得适用于X射线结构分析的晶体。

著录项

来源
《Crystal growth & design》 |2015年第11期|共8页
作者
Boege Matthias; Heck Juergen;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献
中文文献
专利

1. One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System [J] . Boege Matthias, Heck Juergen Crystal growth & design . 2015,第11期

机译：从两相溶剂体系一步制备几乎不溶的钯（II）和铂（II / IV）配合物并进行结晶
2. Trimethyl-palladium(IV) and -platinum(IV) complexes containing phosphine donor ligands, inchuding studies of 1,5,9-triethyl-1,5,9-triphosphacyclodecane and X-ray structural studies of palladium(II) and palladium(IV) complexes [J] . Angela Bayler, Allan J. Canty, Peter G. Edwards, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第19期

机译：含膦供体配体的三甲基钯（IV）和铂（IV）配合物，1,5,9-三乙基-1,5,9-三磷环癸烷的介入研究以及钯（II）和钯（的X射线结构研究） IV）配合物
3. Palladium(II) and platinum(II) complexes with heteroditopic 10-(aryl)phenoxarsine (aryl=2-C6H4OR, R = H, Me, Pr-i) ligands: Solvent-oriented crystallization of cis isomers [J] . Moldovan N, Lonnecke P, Silaghi-Dumitrescu L, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第5期

机译：钯（II）和铂（II）配合物与杂二位10-（芳基）苯恶ar（芳基= 2-C6H4OR，R = H，Me，Pr-i）配体：顺式异构体的溶剂化结晶
4. Preparation and Structures of Alkoxycarbonyl(cyano)palladium(II) Complexes as Intermediates of the Palladium-Catalyzed Cyanoesterification of Norbornenes [C] . Yasushi Nishihara, Mitsuru Miyasaka, Yoshiaki Inoue Symposium on Organometallic Chemistry . 2007

机译：烷氧基羰基（氰基）钯（II）复合物作为钯催化氰基酯化的中间体的烷氧基羰基（Cyano）钯（II）复合物的制备和结构
5. Reactivity studies of platinum(IV) hydroxide and methoxide complexes and the study of pincer palladium(II) complexes as potential catalysts for olefin epoxidation [D] . Smythe, Nicole 2004

机译：氢氧化铂（IV）和甲醇盐配合物的反应性研究以及钳夹钯（II）配合物作为烯烃环氧化潜在催化剂的研究
6. New Platinum(IV) and Palladium(II) Transition Metal Complexes of s-Triazine Derivative: Synthesis, Spectral, and Anticancer Agents Studies [O] . Fatima A. I. Al-Khodir, Hana M. A. Abumelha, Tarfah Al-Warhi, 2006

机译：s-三嗪衍生物的新型铂（IV）和钯（II）过渡金属配合物：合成，光谱和抗癌剂研究
7. Reactivity of Diaryliodine(III) Triflates toward Palladium(II) and Platinum(II): Reactions of C(sp2)-I Bonds to Form Arylmetal(IV) Complexes; Access to Dialkyl(aryl)metal(IV), 1, 4-Benzenediyl-Bridged Platinum(IV), and Triphenylplatinum(IV) Species; and Structural Studies of Platinum(IV) Complexes [O] . -1

机译：二芳基（III）的反应性（III）呈钯（II）和铂（II）：C（SP2）-I键形成芳基金矿（IV）复合物的反应;进入二烷基（芳基）金属（IV），1,4-苯二苯基 - 桥铂（IV）和三苯基铂（IV）物种;铂（IV）复合物的结构研究
8. Reductive Elimination of H-H, H-CH3, and CH3-CH3 from Bis(Phosphine)Platinum(II), - Palladium(II), and -Nickel(II) Complexes: A Theoretical Study Using the SCF-X alpha-SW Method [R] . Balazs, A. C., Johnson, K. H., Whitesides, G. M. 1981

机译：从双（膦）铂（II）， - 钯（II）和-Nickel（II）配合物中还原消除H-H，H-CH3和CH3-CH3：使用sCF-Xα-sW方法的理论研究

One-Step Preparation and Crystallization of Almost Insoluble Palladium(II) and Platinum(II/IV) Complexes from a Biphasic Solvent System

摘要

著录项

相似文献

相关主题

期刊订阅