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首页> 外文期刊>Crystal growth & design >Single-Crystal Structures and Typical Hydrogen-Bonding Motifs of Supramolecular Cocrystals Containing 1,4-Di(1H-imidazol-1-yl)benzene
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Single-Crystal Structures and Typical Hydrogen-Bonding Motifs of Supramolecular Cocrystals Containing 1,4-Di(1H-imidazol-1-yl)benzene

机译:含1,4-二(1H-咪唑-1-基)苯的超分子共晶体的单晶体结构和典型的氢键基序

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摘要

Eight new supramolecular Crystals of 1,4-di(1H-imidazol-1-yl)benzene (DIE) have been prepared using water, 4,4'-biphenol, terephthalic acid, isophthalic acid, succinic acid, and 1,2,4,5-tetrafluoro-3,6-diiodobenzene. These materials were subsequently characterized by single crystal X-ray analysis. The results revealed that one-dimensional infinite chains were formed in these crystals through hydrogen bonding or halogen bonding interactions. The hydrogen atoms of the imidazole ring in DIB were found to be involved in three kinds of hydrogen-bonding ring motifs. These motifs could play an important role in the stabilization of the crystals and could therefore be beneficial to DIB in terms of its role as a good building block for supramolecular crystals.
机译:用水,4,4'-双酚,对苯二甲酸,间苯二甲酸,琥珀酸和1,2,制备了八种新的1,4-二(1H-咪唑-1-基)苯(DIE)的超分子晶体, 4,5-四氟-3,6-二碘苯。随后通过单晶X射线分析对这些材料进行表征。结果表明,通过氢键或卤素键相互作用在这些晶体中形成了一维无限链。发现DIB中咪唑环的氢原子与三种氢键合环基序有关。这些基序可能在稳定晶体中起重要作用,因此就DIB作为超分子晶体的良好构建基块而言,可能对DIB有利。

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