...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Crystal growth & design >Effects of Extending the pi-Electron System of Pillaring Linkers on Fluorescence Sensing of Aromatic Compounds in Two Isoreticular Metal-Organic Frameworks
【24h】

Effects of Extending the pi-Electron System of Pillaring Linkers on Fluorescence Sensing of Aromatic Compounds in Two Isoreticular Metal-Organic Frameworks

机译：扩展柱状接头的pi电子体系对两个等规金属-有机骨架中芳族化合物的荧光传感的影响

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A new porous metal-organic framework (TMU-21) that is isostructural to our recently reported TMU-6 is introduced. The structure of this framework has been determined by X-ray crystallography and further characterized by Fourier transform infrared spectroscopy, elemental analysis, and thermogravimetric analysis. Its structural features as well as its stability and porosity were studied. These two metal-organic frameworks are interesting candidates for a comparative fluorescence study. Thus, their potential abilities to sense nitrobenzene, benzene, and polycyclic aromatic hydrocarbons, namely, naphthalene, anthracene, and pyrene, were investigated. This study clearly shows an important contribution of extending the pi-electron systems of pillaring linkers in the ability of metal-organic frameworks to sense aromatic compounds.
机译：介绍了一种与我们最近报道的TMU-6具有同构结构的新型多孔金属有机骨架（TMU-21）。该框架的结构已通过X射线晶体学确定，并进一步通过傅里叶变换红外光谱，元素分析和热重分析进行了表征。研究了它的结构特征，稳定性和孔隙率。这两个金属有机骨架是进行荧光比较研究的有趣候选对象。因此，研究了它们感测硝基苯，苯和多环芳烃即萘，蒽和pyr的潜在能力。这项研究清楚地表明了扩展柱状连接体的π电子体系对金属有机骨架感测芳族化合物的能力的重要贡献。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号