A new multifunctional enantiopure ligand, (S)-2-(1,8-naphthalimido)-3-(4-imidazole)propanoate (s-nip), containing a homochiral center derived from l-histidine and a strong pi center dot center dot center dot pi stacking 1,8-naphthalimide synthon, has been used to prepare three novel metalorganic frameworks. The frameworks of [Zn(s-nip)(2)](n) (1) and {[Co(s-nip)(2)]center dot(H2O)(0.5)}(n) (2) are isostructural three-dimensional (3D) homochiral supramolecular structures organized one-dimensional (1D) ribbons by strong hydrogen bonds and pi center dot center dot center dot pi interactions, which display ferroelectric behavior at room temperature. The complex [Cu(nia)(2)center dot(H2O)(5)](n) (3) was constructed under a hydrothermal in situ ligand synthesis reaction, in which the new ligand 2-(1,8-naphthalimido)-3-(4-imidazole)acrylate (nia) was formed from the s-nip ligand via a dehydrogenation reaction. The two-dimensional network of 3 stacks into a 3D structure via pi center dot center dot center dot pi interactions resulting in 1D hydrophilic channels.
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