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Formation of an infinite three-dimensional water network by the hierarchic assembly of bilayer water nanotubes of octamers

机译:通过八聚体双层水纳米管的分层组装形成无限的三维水网络

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摘要

A novel three-dimensional water network containing both coordinated and lattice water molecules was obtained in the compound [Co-2(BPTC)(H2O)(6)](n)center dot 11nH(2)O (1). The water network was formed by the hierarchic assembly of bilayer water nanotubes of octamers with crisscross pentamers and helical water chains. A startling feature is the large (H2O)(36) water crowns in the water layer in the [001] plane. Leaving the water molecules from the coordination spheres out of consideration, the water network is a two-dimensional water layer formed by T5(2)5(3) water tapes.
机译:在化合物[Co-2(BPTC)(H2O)(6)](n)中心点11nH(2)O(1)中获得了同时包含配位和晶格水分子的新型三维水网络。水网络是由八角形分子的双层水纳米管的层级组装形成的,该分子具有纵横交错的五聚体和螺旋水链。令人吃惊的特征是[001]平面中水层中的大(H2O)(36)水冠。不考虑配位域中的水分子,水网络是由T5(2)5(3)水带形成的二维水层。

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