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首页> 外文期刊>Crystal growth & design >Controlled synthesis of nearly monodispersed Mn-2(PO4)Cl nanocrystals and nanorods
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Controlled synthesis of nearly monodispersed Mn-2(PO4)Cl nanocrystals and nanorods

机译:几乎单分散的Mn-2(PO4)Cl纳米晶体和纳米棒的受控合成

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摘要

A facile means for obtaining nearly monodispersed Mn-2(PO4)Cl nanocrystals and nanorods with controlled aspect ratios is presented. It has been shown that the obtained Mn-2(PO4)Cl has an orthorhombic structure. Uniform Mn-2(PO4)Cl nanocrystals of about 20 nm and nanorods with diameters of 50-75 nm and lengths of 200-450 nm have been successfully synthesized by a solvothermal microemulsion method under mild conditions, and the aspect ratios of as-obtained nanorods can be properly adjusted by altering the [H2O]/[surfactant] molar ratios. The possible formation mechanisms of nanoparticles and nanorods were proposed and were supported by high-resolution transmission electron microscopy (HRTEM) observations and superior dispersity in nonpolar solvents.
机译:提出了一种简便的方法来获得纵横比受控的几乎单分散的Mn-2(PO4)Cl纳米晶体和纳米棒。已经表明,获得的Mn-2(PO4)Cl具有正交晶结构。溶剂热微乳液法在温和条件下成功合成了约20 nm的均匀Mn-2(PO4)Cl纳米晶体和直径为50-75 nm,长度为200-450 nm的纳米棒,并获得了长径比可以通过改变[H2O] / [表面活性剂]的摩尔比来适当地调节纳米棒。提出了纳米颗粒和纳米棒的可能形成机理,并得到高分辨率透射电子显微镜(HRTEM)观察和在非极性溶剂中优异的分散性的支持。

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