A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene

Zhang B; Pratt FL; Kurmoo M; Okano Y; Kobayashi H; Zhu D

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A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene

机译：杂化有机-无机导体κ-BETS2FeCl4，BETS =双（乙烯二硫代）四硒富勒烯

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A hybrid organic-inorganic conductor kappa'-BETS2FeCl4 is obtained by an electrocrystallization method from BETS and (Me4N)(3)Fe(C2O4)(3) dissolved in a mixture of C6H5Cl and C2H5OH under 2.0 V for 4 weeks. It belongs to the monoclinic space group C2/c, with cell parameters a = 37.783(9), b = 11.207(3), c = 8.530(2) angstrom, beta = 94.835(1)degrees, V = 3598.8(1.4) angstrom(3), and Z = 4. The donor arrangement resembles the kappa-phase but is different to that of the previously reported antiferromagnetic superconductor kappa-BETS2FeCl4, which is orthorhombic and has been studied for 10 years. The inorganic anion exists in two opposite configurations in the anion sheet Of kappa'-BETS2FeCl4, and its crystal structure and electronic structure are different from those of the polymorphs lambda-BETS2FeCl4 and kappa-BETS2FeCl4.

机译：通过电结晶方法，从BETS和在2.0 V下溶解于C6H5Cl和C2H5OH的混合物中的（Me4N）（3）Fe（C2O4）（3），通过电结晶方法获得混合有机-无机导体κ-BETS2FeCl4，历时4周。它属于单斜空间群C2 / c，单元参数a = 37.783（9），b = 11.207（3），c = 8.530（2）埃，beta = 94.835（1）度，V = 3598.8（1.4）（（3），Z =4。施主的排列类似于κ相，但不同于先前报道的反铁磁超导体κ-BETS2FeCl4，它是正交的，已经研究了10年。无机阴离子以两种相反的形态存在于kappa'-BETS2FeCl4的阴离子片中，其晶体结构和电子结构与多晶型lambda-BETS2FeCl4和kappa-BETS2FeCl4的晶体结构和电子结构不同。

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《Crystal growth & design》 |2007年第12期|共5页
作者
Zhang B; Pratt FL; Kurmoo M; Okano Y; Kobayashi H; Zhu D;
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正文语种 eng
中图分类晶体学;
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CHARGE-TRANSFER SALTS; MAGNETIC ANIONS; SUPERCONDUCTING TRANSITIONS; CRYSTAL-STRUCTURE; METALS; THETA; BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE; BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE; TETRATHIAFULVALENE; PHASES;

机译：电荷转移盐;磁性阴离子;超导转变;晶体结构;金属;θ;双（乙二酸）-四硫富瓦烯;双（乙二酸）四硫代富勒烯;四硫代富勒烯;相;

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1. A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene [J] . Zhang B, Pratt FL, Kurmoo M, Crystal growth & design . 2007,第12期

机译：杂化有机-无机导体κ-BETS2FeCl4，BETS =双（乙烯二硫代）四硒富勒烯
2. A new kappa-type organic superconductor based on BETS molecules, kappa-(BETS)(2)GaBr4 [BETS = bis(ethylenedithio)tetraselenafulvalene] [J] . Tanaka H., Fujiwara H., Nakazawa Y., Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology . 2000,第2期

机译：一种基于BETS分子的新型κ型有机超导体，κ-（BETS）（2）GaBr4 [BETS =双（乙烯二硫）四硒富勒烯]
3. Molecular Conductors Based on the Mixed-Valence Polyoxometalates [SMo12O40](n-) (n=3 and 4) and the Organic Donors Bis(ethylenedithio)tetrathiafulvalene and Bis(ethylenedithio)tetraselenafulvalene [J] . Coronado E, Curreli S, Gimenez-Saiz C, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2009,第23期

机译：基于混合价多金属氧酸盐[SMo12O40]（n-）（n = 3和4）和有机给体双（乙烯二硫代）四硫富瓦烯和双（乙烯二硫代）四硒富瓦烯的分子导体
4. Superconductivity and magnetism of BETS conductors (BETS=bis(ethylenedithio)tetraselenafulvalene) [C] . H. KOBAYASHI. (Institute for Molecular Science China-Japan joint symposium on conduction and photoconduction in organic solids and related phenomena;CJOSS-7 . 2001

机译：BETS导体的超导性和磁性（BETS =双（乙烯二硫）四硒富勒烯）
5. Physical and functional interaction between Sindbis virus and neurons: nsP3 macro domain, PARP-1 and NF-kappa B. [D] . Park, Eunhye. 2009

机译：Sindbis病毒与神经元之间的物理和功能相互作用：nsP3宏域，PARP-1和NF-κB。
6. Regioselective synthesis of chiral dimethyl-bis(ethylenedithio)tetrathiafulvalene sulfones [O] . Flavia Pop, Narcis Avarvari 2015

机译：区域选择性合成手性二甲基-双（亚乙基二硫代）四硫富瓦烯砜
7. Hybrid Organic-Inorganic Conductor with a Magnetic Chain Anion: k-BETS2FeIII(C2O4)Cl2 BETS = Bis(ethylenedithio)tetraselenafulvalene [O] . -1

机译：具有磁链阴离子的杂种有机 - 无机导体：K-Bets2 FeiII（C2O4）Cl2 Bets =双（乙二硝酸乙基噻嗪）四氧化甲醛
8. Synthesis and Characterization of Radical Cation Salts ofBis(Ethylenedithio)Tetraselenafulvalene [R] . Montgomery, L. K., Burgin, T., Huffman, J. C., 1993

机译：双（乙二硫代）四萘基富瓦烯的自由基阳离子盐的合成与表征

A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene

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