Supramolecular aggregation of Pd(II) monohelicates directed by discrete (H2O)(8) clusters in a 1,4-diaxially substituted hexameric chairlike conformation

Lopez MV; Zaragoza G; Otero M; Pedrido R; Rama G; Bermejo MK

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Supramolecular aggregation of Pd(II) monohelicates directed by discrete (H2O)(8) clusters in a 1,4-diaxially substituted hexameric chairlike conformation

机译：Pd（II）单螺旋的超分子聚集由离散的（H2O）（8）簇以1,4-双轴取代的六聚体椅子样构象指示

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摘要

We report the first structural evidence in the solid state of discrete water octamers with a 1,4-diaxially substituted hexameric chairlike conformation. These units were found to act as supramolecular glue in the aggregation of Pd(II) monohelicates to give a threedimensional network through hydrogen-bonding.

机译：我们报告了离散的水八聚体的固态，具有1,4-双轴取代的六聚体椅子样构象的第一个结构证据。发现这些单元在Pd（II）单螺旋化合物的聚集中起超分子胶的作用，通过氢键形成三维网络。

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《Crystal growth & design》 |2008年第7期|共4页
作者
Lopez MV; Zaragoza G; Otero M; Pedrido R; Rama G; Bermejo MK;
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正文语种 eng
中图分类晶体学;
关键词
TRANSITION-METAL COMPLEXES; OCTAMERIC WATER CLUSTER; COORDINATION POLYMERS; NEUTRON-DIFFRACTION; SCHIFF-BASE; LIGAND; STATE; ACID; SUBSTRUCTURES; NETWORK;

机译：过渡金属络合物;团簇;配位聚合物;中子衍射;席夫夫碱;配体;状态;酸;子结构;网络;

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1. Supramolecular aggregation of Pd(II) monohelicates directed by discrete (H2O)(8) clusters in a 1,4-diaxially substituted hexameric chairlike conformation [J] . Lopez MV, Zaragoza G, Otero M, Crystal growth & design . 2008,第7期

机译：Pd（II）单螺旋的超分子聚集由离散的（H2O）（8）簇以1,4-双轴取代的六聚体椅子样构象指示
2. Tuning the topologies of Co(II) and Ni(II) complexes with EDTA, 1,3-PDTA and 1,4-BDTA ligands: Synthesis and spectroscopic data of [Mg(H2O)(6)][Co(1,4-bdta)]center dot 3H(2)O and [Mg(H2O)(6)] [Ni(1,4-bdta)] center dot 3H(2)O complexes, and the X-ray [J] . Radanovic DD, Rychlewska U, Warajtis B, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第17期

机译：用EDTA，1,3-PDTA和1,4-BDTA配体调整Co（II）和Ni（II）配合物的拓扑：[Mg（H2O）（6）] [Co（1,4）的合成和光谱数据-bdta]中心点3H（2）O和[Mg（H2O）（6）] [Ni（1,4-bdta）]中心点3H（2）O络合物和X射线
3. Polyoxometalates Paneling through {MO_2O_2S_2} Coordination: Cation-Directed Conformations and Chemistry of a Supramolecular Hexameric Scaffold [J] . Jerome Marrot, Marie Anne Pilette, Mohamed Haouas, Journal of the American Chemical Society . 2012,第3期

机译：通过{MO_2O_2S_2}配位的多金属氧酸盐镶板：阳离子指导的构象和超分子六聚支架的化学。
4. IRMPD and DFT Investigation of Discrete, Anionic Group II Metal Nitrate Clusters [C] . Christopher M. Leavitt, Jos Oomens, Jeffrey Steill, ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：离散，阴离子族II金属硝酸盐簇的IRMPD和DFT调查
5. Synthesis of supramolecular iron (III) complexes by cluster aggregation. [D] . Seddon, Elisa Joy. 2000

机译：通过团簇聚合合成超分子铁（III）配合物。
6. Supramolecular assembled of hexameric water clusters into a 1D chain containing (H2O)6 and (H2O)4O2 stabilized by hydrogen bonding in a copper complex [O] . Masoumeh Tabatabaee 2012

机译：将六聚体水簇超分子组装成一维链该链包含通过氢键稳定在铜配合物中的（H2O）6和（H2O）4O2
7. Supramolecular assembled of hexameric water clusters into a 1D chain containing (H2O)6 and (H2O)4O2 stabilized by hydrogen bonding in a copper complex [O] . Masoumeh Tabatabaee 2012

机译：将六聚体水簇超分子组装成一维链，该链包含通过氢键稳定在铜配合物中的（H2O）6和（H2O）4O2

Supramolecular aggregation of Pd(II) monohelicates directed by discrete (H2O)(8) clusters in a 1,4-diaxially substituted hexameric chairlike conformation

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