Two distinct supramolecular motifs from bis(2-methylimidazo-1-yl) methane: An infinite [n]Catenane and a discrete M6 metal-organic framework

Jin CM; Wu LY; Lu H; Xu Y

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Two distinct supramolecular motifs from bis(2-methylimidazo-1-yl) methane: An infinite [n]Catenane and a discrete M6 metal-organic framework

机译：双（2-甲基咪唑-1-基）甲烷的两个不同的超分子基序：无限[n]癸烷和离散的M6金属-有机骨架

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Two distinct supramolecular motifs, [Ag-4(2-mBIM)(4)(BF4)(4)H2O](n) (1) and [Ag-6(2-mBIM)(6)(SO3CF3)(6)](n) (2), were self-assembled from the ligand bis(2-methylimidazo-1-yl) methane (2-mBIM) and AgBF4 or AgSO3CF3. Their structure was characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. Compound 1 is a 1D infinite [n]catenane molecule, and compound 2 is a discrete M-6 metal-organic framework with a chair conformation like that of cyclohexane.

机译：两个不同的超分子基序[Ag-4（2-mBIM）（4）（BF4）（4）H2O]（n）（1）和[Ag-6（2-mBIM）（6）（SO3CF3）（6）由配体双（2-甲基咪唑-1-基）甲烷（2-mBIM）和AgBF4或AgSO3CF3自组装]（n）（2）。它们的结构通过元素分析，红外光谱和单晶X射线衍射来表征。化合物1是一维无限大[n]环烷分子，化合物2是具有类似环己烷构型的分立构型的M-6金属-有机骨架。

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《Crystal growth & design》 |2008年第1期|共4页
作者
Jin CM; Wu LY; Lu H; Xu Y;
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正文语种 eng
中图分类晶体学;
关键词
COORDINATION POLYMERS; BRIDGING LIGANDS; AG(I) COMPLEXES; NETWORKS; SILVER; ASSEMBLIES; MOLECULES; ISOMERISM; TOPOLOGY; EXAMPLE;

机译：配位聚合物;架桥基;AG（I）络合物;网络;银;组装;分子;异构;拓扑;实例;

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1. Two distinct supramolecular motifs from bis(2-methylimidazo-1-yl) methane: An infinite [n]Catenane and a discrete M6 metal-organic framework [J] . Jin CM, Wu LY, Lu H, Crystal growth & design . 2008,第1期

机译：双（2-甲基咪唑-1-基）甲烷的两个不同的超分子基序：无限[n]癸烷和离散的M6金属-有机骨架
2. Supramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs [J] . AbdulHalim Rasha G., Shkurenko Aleksander, Alkordi Mohamed H., SIAM journal on applied dynamical systems . 2017,第2期

机译：金属有机骨架的超分子异构体衍生自部分柔性配体，具有不同的粘合基序
3. Supramolecular Isomers of Metal-Organic Frameworks Derived from a Partially Flexible Ligand with Distinct Binding Motifs [J] . AbdulHalim Rasha G., Shkurenko Aleksander, Alkordi Mohamed H., Crystal growth & design . 2016,第2期

机译：金属有机骨架的超分子异构体衍生自具有不同结合基序的部分柔性配体。
4. EFFECTS OF THE FRAMEWORK ON ADSORPTION OFMETHANE ON IRMOF-1, IRMOF-2 AND IRMOF-6 METAL-ORGANIC FRAMEWORKS: A COMBINED QM AND MMSTUDY [C] . BUNDET BOEKFA, SAOWAPAK CHOOMWATTANA, CHULARAT WATTANAKIT, International Symposium on Nanoporous Materials . 2008

机译：框架对Irmof-1，Irmof-2和Irmof-6金属 - 有机框架吸附的影响：一种QM和MMStudy
5. Metal-organic Frameworks, including High-throughput Synthesis of Zeolitic Imidazolate Frameworks, and Their Applications in Carbon Dioxide Capture, Storage and as Catalysts for Methane Activation [D] . Phan, Anh Thi Phuong 2011

机译：金属有机骨架，包括高通量合成沸石咪唑酸酯骨架，及其在二氧化碳捕获，储存和甲烷活化催化剂中的应用
6. Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design Synthesis and Functionality of Metal-Organic Materials [O] . Timothy R. Cook, Yao-Rong Zheng, Peter J. Stang -1

机译：金属有机骨架和自组装超分子配合物的：比较和对比金属有机材料的设计合成和功能
7. Porous Metal-Organic Frameworks Based on Metal-Organic Polyhedra with Nanosized Cavities as Supramolecular Building Blocks: Two-Fold Interpenetrating Primitive Cubic Networks of Cu6L812+ Nanocages [O] . -1

机译：基于金属 - 有机多面体的多孔金属有机框架，纳米型空腔作为超分子构建块：Cu6L8 12+纳米病的双折服基元立方网络

Two distinct supramolecular motifs from bis(2-methylimidazo-1-yl) methane: An infinite [n]Catenane and a discrete M6 metal-organic framework

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