In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks

Lin SH; Zhou XP; Li D; Ng SW

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In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks

机译：原位形成的胍盐阳离子作为模板直接制备蜂窝状CuCN网络

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The solvothermal reaction of CuSCN and 1,2-bis(diphenylphosphino)ethane (dppe) in mixed solvents acetonitrile-hexane/(methanol or ethanol) gave a honeycomb-like guanidinium cyanocuprate [C(NH2)(3))]center dot Cu-2(CN)(3)]. The in situ formed cations C(NH2)(3)(+) act as templates to direct the formation of the CuCN network in which multiple weak N-H center dot center dot center dot center dot N/C hydrogen interactions potentially exist between the cations C(NH2)(3)(+) and the {CuCN}(6) rings.

机译：CuSCN与1,2-双（二苯基膦基）乙烷（dppe）在混合溶剂乙腈/正己烷/（甲醇或乙醇）中的溶剂热反应得到蜂窝状氰基铜氰酸胍[C（NH2）（3））]中心点Cu-2（CN）（3）]。原位形成的阳离子C（NH2）（3）（+）作为模板来指导CuCN网络的形成，其中阳离子C之间可能存在多个弱NH中心点中心点中心点中心点N / C氢相互作用（NH2）（3）（+）和{CuCN}（6）环。

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《Crystal growth & design》 |2008年第11期|共3页
作者
Lin SH; Zhou XP; Li D; Ng SW;
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正文语种 eng
中图分类晶体学;
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COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SODALITE TOPOLOGY; BUILDING-BLOCK; SOLID-STATE; COMPLEXES; CARBONATE; COPPER(I); LIGANDS; FRAMEWORK;

机译：配位聚合物;晶体结构;钠盐拓扑学;砌块;固态;复合物;碳酸盐;铜（I）;液体;框架;

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1. In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks [J] . Lin SH, Zhou XP, Li D, Crystal growth & design . 2008,第11期

机译：原位形成的胍盐阳离子作为模板直接制备蜂窝状CuCN网络
2. Synthesis and structural characterization of Zn(II) and Cd(II) ion directed coordination networks and their template-free fabrication to metal oxide nanomaterials [J] . Inorganica Chimica Acta . 2020,第期

机译：Zn（II）和CD（II）离子定向配位网络的合成和结构表征及其对金属氧化物纳米材料的无模板制备
3. In situ fabrication of Cu_(2-x)Se networks nanostructure counter electrode based on Ti substrate via sacrifice template method for quantum dot sensitized solar cells [J] . Chen Yifan, nWag Dejun, Lin Yanhong, Solar Energy . 2019,第Octa期

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4. Solid freeform fabrication of composities by direct deposition and by in situ mineralization [C] . Paul Calvert, Jiong Peng, Chad Souvignier, Symposium on solid freeform and additive fabrication . 1999

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5. Self-assembly and nanofabrication approaches towards photonics and plasmonics: Part I: Directed assembly of inorganic nanostructures through chemical and biomimetic templating. Part II: Fabrication of plasmon resonant structures for surface-enhanced sensing and fluorescence. [D] . Zin, Melvin T. 2007

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6. In situ Fabrication of Multi-Walled Carbon Nanotubes/Silica Hybrid Colloidosomes by Pickering Emulsion Templating Using Trialkoxysilanes of Opposite Polarity [O] . Franziska Grzegorzewski, Avital Benhaim, Yafit Itzhaik Alkotzer, 2019

机译：通过使用相反极性的三烷氧基硅烷的Pickering乳液模板原位制备多壁碳纳米管/二氧化硅杂化胶体
7. Facile Fabrication of Honeycomb-like Carbon Network-Encapsulated Fe/Fe3C/Fe3O4 with Enhanced Li-Storage Performance [O] . -1

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In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks

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