A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3) [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal

Carlucci L; Ciani G; Maggini S; Proserpio DM

首页> 外文期刊>Crystal growth & design >A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3) [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal

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A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3) [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal

机译：[Mn-2（bix）（3）（NO3）（4）]中心点2CHCl（3）[bix = 1,4-bis（imidazol-1）中的交错2D砖墙层和ID分子梯的新的多级3D阵列-基甲基）苯]在去除客体后进行超分子异构化

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The reactions of Mn(II) nitrate with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) (reagent ratios 1:2-1:3) yield novel interesting coordination networks including, besides the ladder-like species [Mn(bix)(1.5)(NO3)(2)] and the 2-fold interpenetrated three-dimensional (3D) cds network [Mn(bix)(2)(NO3)(2)], the exceptional [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3), which is comprised of two different supramolecular isomers, namely, brickwall layers and one-dimensional (ID) molecular ladders, polycatenated to give a 3D (2D + 1D) architecture.

机译：硝酸锰（II）与灵活的配体1,4-双（咪唑-1-基甲基）苯（bix）（试剂比例为1：2-1：3）的反应产生了新的有趣的配位网络，除了梯形-相似的物种[Mn（bix）（1.5）（NO3）（2）]和2倍互穿的三维（3D）cds网络[Mn（bix）（2）（NO3）（2）]， Mn-2（bix）（3）（NO3）（4）]中心点2CHCl（3），由两种不同的超分子异构体，即砖墙层和一维（ID）分子梯组成，将其多链化即可得到3D（2D + 1D）架构。

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《Crystal growth & design》 |2008年第1期|共4页
作者
Carlucci L; Ciani G; Maggini S; Proserpio DM;
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正文语种 eng
中图分类晶体学;
关键词
COORDINATION POLYMERS; NETWORKS; FRAMEWORKS; CRYSTAL; NETS; POLYROTAXANE; ARCHITECTURE; CHEMISTRY; 1; 4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE; INTERPENETRATION;

机译：配位聚合物;网络;框架;晶体;网;聚氧杂烷;建筑;化学;1;4-双（咪唑-1-甲基）苯;互穿;

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1. A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3) [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal [J] . Carlucci L, Ciani G, Maggini S, Crystal growth & design . 2008,第1期

机译：[Mn-2（bix）（3）（NO3）（4）]中心点2CHCl（3）[bix = 1,4-bis（imidazol-1）中的交错2D砖墙层和ID分子梯的新的多级3D阵列-基甲基）苯]在去除客体后进行超分子异构化
2. An Infinite 2D Polyrotaxane Network in Ag_2(bix)_3(NO_3)_2 (bix = 1,4-Bis(imidazol-1-ylmethyl)benzene) [J] . Bernard F. Hoskins, Richard Robson, Damian A. Slizys Journal of the American Chemical Society . 1997,第12期

机译：Ag_2（bix）_3（NO_3）_2（bix = 1,4-双（咪唑-1-基甲基）苯）中的无限二维聚轮烷网络
3. Neutral coordination polymers based on a metal-mono(dithiolene) complex: Synthesis, crystal structure and supramolecular chemistry of [Zn(dmit)(4,4′-bpy)]_n, [Zn(dmit)(4,4′-bpe)]_n and [Zn(dmit)(bix)]_n (4,4′-bpy = 4,4′-bipyridine, 4,4′-bpe = trans-1,2-bis(4-pyridyl)ethene, bix = 1,4-bis(imidazole-1- ylmethyl)-benzene [J] . Madhu V., Das S.K. Dalton transactions: An international journal of inorganic chemistry . 2011,第48期

机译：基于金属-单（二硫醇）配合物的中性配位聚合物：[Zn（dmit）（4,4'-bpy）] _ n，[Zn（dmit）（4,4'-bpe）的合成，晶体结构和超分子化学）] _ n和[Zn（dmit）（bix）] _ n（4,4'-bpy = 4,4'-联吡啶，4,4'-bpe =反-1,2-双（4-吡啶基）乙烯， bix = 1,4-双（咪唑-1-基甲基）苯

A new polycatenated 3D array of interlaced 2D brickwall layers and ID molecular ladders in [Mn-2(bix)(3)(NO3)(4)]center dot 2CHCl(3) [bix=1,4-bis(imidazol-1-ylmethyl)benzene] that undergoes supramolecular isomerization upon guest removal

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