Solvent Effect on Pseudopolymorphism of Hemicyclohexylcucurbit[6]uril

Li YT; Li L; Zhu YP; Meng XG; Wu AX

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Solvent Effect on Pseudopolymorphism of Hemicyclohexylcucurbit[6]uril

机译：溶剂对半环己基葫芦[6] uril假多态性的影响

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Novel covalent macrocycle, hmcyCuc6, has been synthesized and its four pseudopolymorphs were reported. HmcyCuc6 is highly selective to CH2Cl2, CHCl3, and CCl4 in the crystal growth, and the selectivity of the hmcyCuc6 toward these solvent molecules may be related to the symmetry of the solvent molecules. In addition, four pseudopolymorphs can be simply controlled by changing the crystallization solvent system. To our best knowledge, the pseudopolymorphism of the cucurbit[n]uril homologues is reported for the first time.

机译：已经合成了新型共价大环hmcyCuc6，并报道了其四个假多晶型物。 HmcyCuc6对晶体生长中的CH2Cl2，CHCl3和CCl4具有高度选择性，并且hmcyCuc6对这些溶剂分子的选择性可能与溶剂分子的对称性有关。另外，可以通过改变结晶溶剂体系来简单地控制四种假多晶型物。据我们所知，首次报道了葫芦[n] uril同源物的假多态性。

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《Crystal growth & design》 |2009年第10期|共3页
作者
Li YT; Li L; Zhu YP; Meng XG; Wu AX;
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正文语种 eng
中图分类 549B0001;
关键词
INDUCED SUPRAMOLECULAR ISOMERISM; HOST-GUEST COMPLEX; INCLUSION COMPLEXES; UNSOLVATED HOSTS; POLYMORPHISM; FRAMEWORKS; DIANILINEGOSSYPOL; POLARITY; SYSTEM; ACID;

机译：诱导的超分子异构;客座复合体;包含复合体;未溶解的宿主;多态性;框架;对苯二酚;极性;系统;酸;

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1. Solvent Effect on Pseudopolymorphism of Hemicyclohexylcucurbit[6]uril [J] . Li YT, Li L, Zhu YP, Crystal growth & design . 2009,第10期

机译：溶剂对半环己基葫芦[6] uril假多态性的影响
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3. Solvent-induced stable pseudopolymorphism of Au(I)-thiolate lamellar assemblies: a model system for understanding the environment acclimation of biomacromolecules [J] . Hao Yajiao, Dai Chuying, Yu Lin, CrystEngComm . 2018,第2期

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4. Binding Selectivity of Cucurbit5uril (CB5) and Substituted Cucurbit5uril For Anions in the Gas Phase [C] . Jiewen Shen, David V. Dearden ASMS Conference on Mass Spectrometry and Allied Topics . 2015

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5. A Study of Host-guest relationship between Cucurbit [n] uril and N-2-aryl-1, 2, 3 triazole. [D] . Aparaj, Siddhita H. 2013

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6. Variational Implicit-Solvent Modeling of Host–GuestBinding: A Case Study on Cucurbit7uril [O] . Shenggao Zhou, KathleenE. Rogers, César Augusto F. de Oliveira, -1

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7. Solvent induced polymorphism and pseudopolymorphism among fullerene C60organic adducts [O] . A. Gubaidullin, A. Saifina 2011

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Solvent Effect on Pseudopolymorphism of Hemicyclohexylcucurbit[6]uril

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