Microporous metal-organic framework based on supermolecular building blocks (SBBs): Structure analysis and selective gas adsorption properties

Chang Z.; Zhang D.-S.; Hu T.-L.; Bu X.-H.

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Microporous metal-organic framework based on supermolecular building blocks (SBBs): Structure analysis and selective gas adsorption properties

机译：基于超分子构件（SBB）的微孔金属有机骨架：结构分析和选择性气体吸附特性

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A new supermolecular building blocks (SBBs) based microporous metal-organic framework (MOF) was prepared with both 1,3,5-benzenetricarboxylic acid (H 3btc) and 2,4,6-tris(4-pyridyl)-1,3,5-triazine (tpt) as ligands. The obtained Co~(II) MOF reveals an uncommon ftw-a-like structure from the assembly of cubohemioctahedra SBBs under the direction of tpt and exhibits selective gas adsorption properties depending on gas molecule diameter and temperature which might have application in gas separation purposes.

机译：用1,3,5-苯三甲酸（H 3btc）和2,4,6-三（4-吡啶基）-1,3制备了一种新的基于超分子构件（SBBs）的微孔金属有机骨架（MOF），5-三嗪（tpt）作为配体。所获得的Co-（II）MOF在tpt方向上由立方半八面体SBB的组装体显示出不常见的类似ftw-a的结构，并且根据气体分子的直径和温度表现出选择性的气体吸附特性，这可能在气体分离目的中应用。

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《Crystal growth & design》 |2011年第6期|共4页
作者
Chang Z.; Zhang D.-S.; Hu T.-L.; Bu X.-H.;
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正文语种 eng
中图分类晶体学;
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1. Microporous metal-organic framework based on supermolecular building blocks (SBBs): Structure analysis and selective gas adsorption properties [J] . Chang Z., Zhang D.-S., Hu T.-L., Crystal growth & design . 2011,第6期

机译：基于超分子构件（SBB）的微孔金属有机骨架：结构分析和选择性气体吸附特性
2. Novel metal-organic framework based on cubic and trisoctahedral supermolecular building blocks: Topological analysis and photoluminescent property [J] . Zhao X., Wang S., Dou J., Crystal growth & design . 2012,第6期

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3. Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks [J] . Farid Nouar, Jarrod F. Eubank, Till Bousquet, Journal of the American Chemical Society . 2008,第6期

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4. Synthesis, structure and selective adsorption property of Zn metal-organic framework [C] . Yu-Ling Li, Yu-Fei Wang, Li-Ping Zheng, International Conference on Advances in Energy and Environmental Research . 2018

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5. Supramolecular structures and metal-organic frameworks based on metal dipyrrin building blocks. [D] . Halper, Sara R. 2006

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6. Selective Adsorption-Based Separation of Flue Gas and Natural Gas in Zirconium Metal-Organic Frameworks Nanocrystals [O] . Pengli Li, Yongli Shen, Dandan Wang, 2019

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7. Structure, Luminescence, and Adsorption Properties of Two Chiral Microporous Metal-Organic Frameworks [O] . -1

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Microporous metal-organic framework based on supermolecular building blocks (SBBs): Structure analysis and selective gas adsorption properties

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