New fluoride borate solid-solution series Ba _(4-x)Sr _(3+x)(BO _3) _(4-y)F _(2+3y)

Rashchenko S.V.; Bekker T.B.; Bakakin V.V.; Seryotkin Y.V.; Shevchenko V.S.; Kokh A.E.; Stonoga S.Y.

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New fluoride borate solid-solution series Ba _(4-x)Sr _(3+x)(BO _3) _(4-y)F _(2+3y)

机译：新型氟化硼酸盐固溶体系列Ba _（4-x）Sr _（3 + x）（BO _3）_（4-y）F _（2 + 3y）

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A lot of attention has been paid recently to the non-centrosymmetric fluoride borates with chemical formula BaMBO _3F (M = Ca, Mg, Zn). A new BaSrBO _3F phase has been synthesized by the solid-state reaction, and single crystals have been grown in the BaSrBO _3F-NaF system. According to the X-ray single-crystal structure analysis, the compound crystallizes in the space group P6 3mc. The distinguished feature of the determined structure is the simultaneous cationic (Ba ~(2+) ? Sr ~(2+)) and anionic (3F) ~3- ? (BO _3) ~(3-) isomorphisms, implying the existence of the solid-solution series Ba _(4-x)Sr _(3+x)(BO _3) _(4-y)F _(2+3y). The Ba _4Sr _3(BO _3) _4F _2 and Ba _3Sr _4(BO _3) _4F _2 end-members have been synthesized by solid-state reaction. The existence of Ba _4Sr _3(BO _3) _3F _5 and Ba _3Sr _4(BO _3) _3F _5 end-members has not been confirmed.

机译：最近，化学式为BaMBO _3F（M = Ca，Mg，Zn）的非中心对称氟化硼酸盐受到了广泛关注。通过固相反应合成了新的BaSrBO _3F相，并在BaSrBO _3F-NaF系统中生长了单晶。根据X射线单晶结构分析，该化合物在空间群P6 3mc中结晶。所确定的结构的显着特征是同时存在阳离子（Ba〜（2+）→Sr〜（2+））和阴离子（3F）〜3-？（BO _3）〜（3-）同构，表明存在固溶级数Ba _（4-x）Sr _（3 + x）（BO _3）_（4-y）F _（2 + 3y ）。通过固态反应合成了Ba _4Sr _3（BO _3）_4F _2和Ba _3Sr _4（BO _3）_4F _2端基。尚未确认Ba _4Sr _3（BO _3）_3F _5和Ba _3Sr _4（BO _3）_3F _5末端成员的存在。

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《Crystal growth & design》 |2012年第6期|共6页
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Rashchenko S.V.; Bekker T.B.; Bakakin V.V.; Seryotkin Y.V.; Shevchenko V.S.; Kokh A.E.; Stonoga S.Y.;
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1. New fluoride borate solid-solution series Ba _(4-x)Sr _(3+x)(BO _3) _(4-y)F _(2+3y) [J] . Rashchenko S.V., Bekker T.B., Bakakin V.V., Crystal growth & design . 2012,第6期

机译：新型氟化硼酸盐固溶体系列Ba _（4-x）Sr _（3 + x）（BO _3）_（4-y）F _（2 + 3y）
2. Birefringence of the new fluoride borates Ba2Na3[B3O6](2)F and Ba-7(BO3)(4-y)F2+3y in the Na, Ba, B//O, F quaternary reciprocal system [J] . Bekker T. B., Vedenyapin V. N., Khamoyan A. G. Materials Research Bulletin . 2017,第JULa期

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3. Crystal Growth, Structure, and Properties of a Non-Centrosymmetric Fluoride Borate, Ba3Sr4(BO3)(3)F-5 [J] . Zhang GC, Liu ZL, Zhang JX, Crystal growth & design . 2009,第7期

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4. Photo-Luminescence Study of Red Borate Phosphor Sr_3 Y_(1-x) (BO_3)_3:xEu~(3+) [C] . S.P. Hargunani, R.S. Palaspagar, R.P. Sonekar, International Conference on "Multidimensional Role of Basic Science in Advanced Technology" . 2019

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New fluoride borate solid-solution series Ba _(4-x)Sr _(3+x)(BO _3) _(4-y)F _(2+3y)

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