Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd_4O_(24] and [BrCd_4O_(24)] Clusters

R. Vaidhyanathan; Srinivasan Natarajan; C. N. R. Rao

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Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd_4O_(24] and [BrCd_4O_(24)] Clusters

机译：具有互穿框架的四面体[ClCd_4O_（24）和[BrCd_4O_（24）]簇形成的互穿框架的开放框架琥珀酸镉。

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By carrying out a metathetic reaction between sodium succinate and CdCl_2 or CdBr_2 in an n-butanol-water mixture, two novel open-framework cadmium succinates, [NA_3Cd_5(C_4H_4O_4)_6Cl], I, and [Na_3Cd_5(C_4H_4O_4)_6Br], II, have been isolated. Both of these compounds possess interpenetrating three-dimensional open-framework structures wherein tetrahedral Cl(Br)Cd_4O_(24) clusters are connected by succinate linkages. The tetrahedral cluster itself is formed of four CdO_6 octahedra surrounding a halogen atom. The three-dimensional cadmium succinate framework incorporates sodium ions. Four sodiums surround the second nearest neighbor halogen atom, forming a Na_4Cl(Br) tetrahedron.

机译：通过在正丁醇-水混合物中进行琥珀酸钠与CdCl_2或CdBr_2之间的易位反应，生成了两种新型的开放骨架琥珀酸镉[NA_3Cd_5（C_4H_4O_4）_6Cl]，I和[Na_3Cd_5（C_4H_4O_4），已被隔离。这两种化合物均具有互穿的三维开放框架结构，其中四面体Cl（Br）Cd_4O_（24）簇通过琥珀酸酯键连接。四面体簇本身由围绕卤素原子的四个CdO-6八面体形成。三维琥珀酸镉框架包含钠离子。四个钠围绕第二个相邻的卤素原子，形成Na_4Cl（Br）四面体。

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《Crystal growth & design》 |2003年第1期|共5页
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R. Vaidhyanathan; Srinivasan Natarajan; C. N. R. Rao;
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1. Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd_4O_(24] and [BrCd_4O_(24)] Clusters [J] . R. Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao Crystal growth & design . 2003,第1期

机译：具有互穿框架的四面体[ClCd_4O_（24）和[BrCd_4O_（24）]簇形成的互穿框架的开放框架琥珀酸镉。
2. Open-framework cadmium succinates of different dimensionalities [J] . Vaidhyanathan R., Natarajan S., Rao CNR. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2002,第20期

机译：开放框架的不同尺寸的琥珀酸镉
3. A 3D interpenetrated rutile coordination framework formed by dinuclear cadmium clusters and 4,4'-sulfonyldibenzoate [J] . Dongrong Xiao, Haiyan Chen, Dianzhen Sun Solid state sciences . 2011,第8期

机译：由双核镉簇和4,4'-磺酰基二苯甲酸酯形成的3D互穿金红石协调框架
4. Template-Designed Synthesis of Open-Framework Zinc Phosphites with Extra-Large 24-Ring Channels [C] . Jiyang Li, Li Li, Jihong Yu, 第四届国际分子模拟与信息技术应用学术会议（The 4th International Conference of Molecular Simulations and Applied Informatics Technologies）论文集 . 2008

机译：具有超大24环通道的开放式骨架亚磷酸锌的模板设计合成
5. Ligand combination strategy for the preparation of novel low-dimensional and open-framework metal cluster materials. [D] . Anokhina, Ekaterina V. 2001

机译：配体结合策略，用于制备新型低维和开放框架的金属团簇材料。
6. Bis(μ-24-dihydroxybenzoato-κ2 O:O′)bisaqua(24-dihydroxybenzoato-κO)(110-phenanthroline-κ2 NN′)cadmium(II) [O] . Jing-Jing Nie, Tian-Tian Pan, Jian-Rong Su, 2010

机译：双（μ-24-二羟基苯并-κ2 O：O）bis aqua（24-dihydroxybenzoato-κO）（110-phenothroline-κ2 NN）镉（II）
7. Cover Picture: Supramolecular Open-Framework of a Bipyridinium-Carboxylate Based Copper Complex with High and Reversible Water Uptake (Z. Anorg. Allg. Chem. 24/2016) [O] . Maxime Leroux, Guy Weber, Jean-Pierre Bellat, 2016

机译：封面图片：具有高且可逆的水的铜配合物的超分子开放框架，具有高和可逆的水吐痰（Z.Anorg。Allg。Chem。24/2016）

Open-Framework Cadmium Succinates with Interpenetrating Frameworks Formed by Tetrahedral [ClCd_4O_(24] and [BrCd_4O_(24)] Clusters

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