Room Temperature ZnO Mesocrystal Formation in the Hydrated Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide

Li ZH; Shkilnyy A; Taubert A

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Room Temperature ZnO Mesocrystal Formation in the Hydrated Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide

机译：水合离子液体前体（ILP）氢氧化四丁基铵中的室温ZnO介晶形成

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Zinc oxide particles can be grown from the hydrated ionic liquid precursor (ILP) tetrabutylammonium hydroxide (TBAH) at room temperature. The final particles are micrometers in size and are so-called mesocrystals, that is, larger crystals composed of nanoscale building blocks. Electron microscopy and particle size analysis reveal that, unlike ZnO grown from aqueous solution, the particle number in the TBAH/water mixtures decreases with increasing reaction time. Initially, numerous small particles precipitate. They transform into fewer, but larger, mesocrystals composed of rod-like primary particles.

机译：可以在室温下从水合离子液体前体（ILP）氢氧化四丁铵（TBAH）中生长出氧化锌颗粒。最终粒子的尺寸为微米，是所谓的介观晶体，即由纳米级结构单元组成的较大晶体。电子显微镜和粒度分析表明，与从水溶液中生长的ZnO不同，TBAH /水混合物中的颗粒数随反应时间的增加而减少。最初，许多小颗粒沉淀。它们转变为由棒状初级粒子组成的较少但较大的介晶。

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《Crystal growth & design》 |2008年第12期|共7页
作者
Li ZH; Shkilnyy A; Taubert A;
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正文语种 eng
中图分类晶体学;
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FLUORAPATITE-GELATIN-COMPOSITES; IONOTHERMAL SYNTHESIS; CRYSTAL PRECURSORS; AQUEOUS-SOLUTION; NONCLASSICAL CRYSTALLIZATION; INORGANIC MATERIALS; GOLD NANOPARTICLES; DENATURED COLLAGEN; BLOCK-COPOLYMERS; REAL-STRUCTURE;

机译：氟磷灰石-明胶复合材料;离子热合成;晶体前体;水溶液;非经典结晶;无机材料;金纳米粒子;变性胶原;嵌段共聚物;嵌段共聚物;

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专利

1. Room Temperature ZnO Mesocrystal Formation in the Hydrated Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide [J] . Li ZH, Shkilnyy A, Taubert A Crystal growth & design . 2008,第12期

机译：水合离子液体前体（ILP）氢氧化四丁基铵中的室温ZnO介晶形成
2. CuO Nanopartides from the Strongly Hydrated Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide: Evaluation of the Ethanol Sensing Activity [J] . Andreas Taubert, Franziska Stange, Zhonghao Li ACS applied materials & interfaces . 2012,第2期

机译：强水合离子液体前体（ILP）氢氧化四丁基铵的CuO纳米粒子：乙醇传感活性的评估。
3. Lessons from a “Failed” Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass [J] . Andreas Taubert, Yaroslav Z. Khimyak, Zhonghao Li Materials . 2008,第1期

机译：“失败的”实验的教训：乙酸锌，离子液体前体（ILP）氢氧化四丁基铵（TBAH）和玻璃的反应导致形态复杂的硅酸锌
4. Semi-clathratic impact of tetrabutylammonium hydroxide on the carbon dioxide hydrates [C] . Khor Siak Foo, Muhammad Saad Khan, Bhajan Lal International Conference on Process Engineering and Advanced Materials . 2019

机译：四丁基氢氧化铵对二氧化碳水合物的半克拉语
5. Development of Statistical Associating Fluid Theory for Aqueous Ionic Liquid Solutions by Implementing Monte Carlo Simulations and Ornstein-Zernike Integral Equation: Application to Describing Gas Hydrate Inhibition Performance of Ionic Liquids. [D] . Jiang, Hao. 2014

机译：通过实现蒙特卡洛模拟和Ornstein-Zernike积分方程，发展用于离子液体水溶液的统计缔合流体理论：在描述离子液体的气体水合物抑制性能中的应用。
6. Lessons from a Failed Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH) and Glass [O] . Zhonghao Li, Yaroslav Z. Khimyak, Andreas Taubert 2008

机译：失败的实验的教训：乙酸锌离子液体前体（ILP）氢氧化四丁基铵（TBAH）和玻璃的反应导致形态复杂的硅酸锌
7. Lessons from a Ã¢Â€ÂœFailedÃ¢Â€Â Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass [O] . Andreas Taubert, Yaroslav Z. Khimyak, Zhonghao Li 2008

机译：实验：通过醋酸锌，离子液体前体（ILp）四丁基氢氧化铵（TBaH）和玻璃的反应形成复杂形态的硅酸锌的经验教训
8. A Low Temperature, High Pressure Hydrate of n-Tetrabutylammonium Halides [R] . Horne, R. A., Young, R. P. 1967

机译：一种低温，高压的正四丁基卤化铵水合物

Room Temperature ZnO Mesocrystal Formation in the Hydrated Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide

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