Molecular design strategies for optimizing the nonlinear optical properties of chiral crystals

Wampler RD; Begue NJ; Simpson GJ

首页> 外文期刊>Crystal growth & design >Molecular design strategies for optimizing the nonlinear optical properties of chiral crystals

【24h】

Molecular design strategies for optimizing the nonlinear optical properties of chiral crystals

机译：优化手性晶体非线性光学性质的分子设计策略

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A simple theoretical framework is presented to identify the key molecular properties and macromolecular arrangements leading to high second-order nonlinear optical (NLO) activity of chiral crystals. In chiral materials, maximum second harmonic generation (SHG) efficiency is predicted for an antiparallel molecular arrangement of, A-like chromophores. This prediction is in stark contrast to the majority of previous crystal engineering efforts for second-order NLO materials, which have been focused almost exclusively on the construction of crystals exhibiting high degrees of polar order. Methods for possible rational electrostatic control of crystal structure by appropriate molecular design are considered.

机译：提出了一个简单的理论框架来鉴定导致手性晶体的高二阶非线性光学（NLO）活性的关键分子特性和大分子排列。在手性材料中，对于A类生色团的反平行分子排列，可以预测出最大的二次谐波生成（SHG）效率。该预测与先前针对二阶NLO材料的大多数晶体工程工作形成了鲜明的对比，后者几乎完全专注于显示出高极性序的晶体的构造。考虑了通过适当的分子设计对晶体结构进行合理的静电控制的方法。

著录项

来源
《Crystal growth & design》 |2008年第8期|共6页
作者
Wampler RD; Begue NJ; Simpson GJ;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
BIPYRIDYL METAL-COMPLEXES; 2ND-HARMONIC GENERATION; LIQUID-CRYSTAL; NLO MATERIALS; CHROMOPHORE; HYPERPOLARIZABILITY; PREDICTION; SYMMETRY; ORIGINS; TENSOR;

机译：联吡啶金属络合物;第二代钟晶生成;液体晶体;非接触材料;色度;超极化率;预测;对称性;原点;张量;

相似文献

外文文献
中文文献
专利

1. Molecular design strategies for optimizing the nonlinear optical properties of chiral crystals [J] . Wampler RD, Begue NJ, Simpson GJ Crystal growth & design . 2008,第8期

机译：优化手性晶体非线性光学性质的分子设计策略
2. Strategy for the optical property studies in ultraviolet nonlinear optical crystals from density functional theory [J] . Lin Z.S., Kang L., Zheng T., Computational Materials Science . 2012,第Null期

机译：基于密度泛函理论的紫外非线性光学晶体光学特性研究策略
3. Crystal structure, molecular packing, FMO, NBO, nonlinear optical and optical limiting properties of an organic imidazolium diphenylacetate diphenylacetic acid single crystal [J] . Jauhar Ro. Mu., Era Paavai, Viswanathan V., New Journal of Chemistry . 2018,第4期

机译：晶体结构，分子包装，FMO，NBO，非线性光学和光学限制性的有机咪唑鎓二苯基乙酸二苯基乙酸单晶
4. Enhancement of nonlinear optical properties through supramolecular chirality [C] . S.Van Elshocht, B.Busson, T.Verbiest, Symposium on Organic Nonlinear Optical Materials and Devices, held April 6-9, 1999, San Francisco, California, U.S.A. . 1999

机译：通过超分子手性增强非线性光学性质
5. Second-order nonlinear optical imaging of chiral crystals: Insturmentation and application to protein crystalization. [D] . Kissick, David J. 2012

机译：手性晶体的二阶非线性光学成像：仪器及其在蛋白质结晶中的应用。
6. Screening of Protein Crystallization Trials by Second Order Nonlinear Optical Imaging of Chiral Crystals (SONICC) [O] . Levi Haupert, Garth Simpson -1

机译：二阶非线性光学成像筛选蛋白质结晶试验的手性晶体（SONICC）
7. INFLUENCE OF MOLECULAR AND CRYSTAL STRUCTURE ON NONLINEAR OPTICAL PROPERTIES OF HYDRATED AND ANHYDROUS POTASSIUM L-2-NITRIMINO-1,3-DIAZEPANE-4-CARBOXYLATE CRYSTALS [O] . R.A. Apreyan, A.K. Atanesyan, A.M. Petrosyan 2019

机译：分子和晶体结构对水合钾的非线性光学性能的影响 - 1-二硝基-1,3-二氮杂-4-羧酸晶体的非线性光学性质

Molecular design strategies for optimizing the nonlinear optical properties of chiral crystals

摘要

著录项

相似文献

相关主题

期刊订阅