Morphology control of electrodeposited Cu2O crystals in aqueous solutions using room temperature hydrophilic ionic liquids

Li H; Liu R; Zhao RX; Zheng YF; Chen WX; Xu ZD

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Morphology control of electrodeposited Cu2O crystals in aqueous solutions using room temperature hydrophilic ionic liquids

机译：使用室温亲水性离子液体控制水溶液中电沉积Cu2O晶体的形态

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Room temperature hydrophilic ionic liquids, 1-methyl-3-ethylimidazolium salts containing ethyl-sulfate anions, have dramatic effects on the morphology changes of electrochemically grown Cu2O crystals at room temperature in aqueous solutions. The shape of Cu2O crystals evolves from cubic to octahedral and spherical shape only by adding a varied small amount of the ionic liquids in the deposited solutions. The possible mechanism has been explored, and the ethyl-sulfate anion is believed to play a key role in the morphology control.

机译：室温亲水性离子液体，含有硫酸乙酯的1-甲基-3-乙基咪唑鎓盐对室温下水溶液中电化学生长的Cu2O晶体的形态变化具有显着影响。仅通过在沉积溶液中添加少量的离子液体，即可将Cu2O晶体的形状从立方和八面体演变为球形。已经探索了可能的机制，并且认为硫酸乙酯阴离子在形态控制中起关键作用。

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《Crystal growth & design》 |2006年第12期|共4页
作者
Li H; Liu R; Zhao RX; Zheng YF; Chen WX; Xu ZD;
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正文语种 eng
中图分类晶体学;
关键词
SHAPE-CONTROLLED SYNTHESIS; EPITAXIAL ELECTRODEPOSITION; ZINC-OXIDE; NANOPARTICLES; SOLVENTS; NANOSTRUCTURES; SEMICONDUCTORS; TRANSITION; CATALYSIS; NANOCUBES;

机译：形状控制的合成;表观电沉积;氧化锌;纳米微粒;溶剂;纳米结构;半导体;转变;催化;纳米球;

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1. DMI-LiNO_(3)溶剂化离子液体的物理化学性质及其在室温电沉积钕中的应用 [J] . 刘爱民, 姚宇, 郭梦霞, 中国有色金属学报：英文版 . 2021,第008期
2. Morphology control of electrodeposited Cu2O crystals in aqueous solutions using room temperature hydrophilic ionic liquids [J] . Li H, Liu R, Zhao RX, Crystal growth & design . 2006,第12期

机译：使用室温亲水性离子液体控制水溶液中电沉积Cu2O晶体的形态
3. Interaction of Nonionic Surfactants and Hydrophilic Ionic Liquids in Aqueous Solutions: Can Short Ionic Liquids Be More Than a Solvent? [J] . Francesc Comelles, Isabel Ribosa, Juan José González, Langmuir . 2012,第41期

机译：非离子表面活性剂与亲水性离子液体在水溶液中的相互作用：离子液体短于溶剂是否能比溶剂？
4. Interaction of nonionic surfactants and hydrophilic ionic liquids in aqueous solutions: Can short ionic liquids be more than a solvent? [J] . Comelles F., Ribosa I., González J.J., Langmuir: The ACS Journal of Surfaces and Colloids . 2012,第41期

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5. Crystal Morphology and Molecular Interaction of Lysozyme Affected by Imidazolium-Based Ionic Liquids in Aqueous Solutions [C] . Xiao Huazhi, Dang Leping, Wang Zhanzhong 5th International Conference on Bioinformatics and Biomedical Engineering . 2011

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Morphology control of electrodeposited Cu2O crystals in aqueous solutions using room temperature hydrophilic ionic liquids

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