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Sonochemical preparation of luminescent PbWO4 nanocrystals with morphology evolution

机译:形态演化的声波化学制备发光PbWO4纳米晶体

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摘要

PbWO4 nanostructures with different morphologies, such as polyhedral, spindle-like, and dot-shaped, have been successfully synthesized via a mild sonochemical route from an aqueous solution of lead acetate and sodium tungstate in the presence of complexing reagent NTA. Reaction conditions, such as pH value and the concentration of complexing reagent, were found to have close relation with the morphologies of final products. The ultrasound-induced oriented attachment growth mechanism has been proposed for the possible formation mechanism of spindle-like sample. Raman and room-temperature photoluminescence of PbWO4 samples with different morphologies have also been investigated.
机译:在络合剂NTA的存在下,已通过乙酸钠和钨酸钠的水溶液通过温和的声化学途径成功合成了具有不同形态的PbWO4纳米结构,例如多面体,纺锤状和点状。发现pH值和络合剂浓度等反应条件与最终产物的形态密切相关。已经提出了超声诱导的定向附着生长机制,以用于纺锤状样品的可能形成机制。还研究了不同形态的PbWO4样品的拉曼光谱和室温光致发光。

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