A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carboxylate clusters

Fang QR; Zhu GS; Jin Z; Xue M; Wei X; Wang DJ; Qiu SL

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A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carboxylate clusters

机译：由五核羧酸锌簇簇构筑的具有类金刚石结构的新型金属有机骨架

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A new 3D MOF, [Zn-5(mu(3)-O)(2)(bpdc)(4)(DMF)(2)(EtOH)(2)]center dot 3(DMF)center dot 3(EtOH)center dot 5(H2O) (1) (bpdc = 4,4'-biphenyldicarboxylate, DMF = N,N-dimethylformamide and EtOH = ethanol), has been synthesized under mild conditions. X-ray crystallography reveals that polymer 1 consists of a 3D framework with an expanded diamondoid topology constructed from double 4-connected pentanuclear SBUs linked by rigid bpdc ligands. For an unusual pentanuclear framework, polymer 1 shows the favorable CH3OH adsorption behavior and good optoelectronic effect, which will facilitate the exploration of new types of multifunctional materials.

机译：一种新的3D MOF，[Zn-5（mu（3）-O）（2）（bpdc）（4）（DMF）（2）（EtOH）（2）]中心点3（DMF）中心点3（EtOH））中心点5（H2O）（1）（bpdc = 4,4'-联苯二羧酸酯，DMF = N，N-二甲基甲酰胺，EtOH =乙醇），已在温和条件下合成。 X射线晶体学揭示聚合物1由3D框架组成，该框架具有由刚性bpdc配体连接的双4连接五核SBU构成的扩展的类金刚石拓扑。对于不寻常的五核骨架，聚合物1表现出良好的CH3OH吸附性能和良好的光电效应，这将有助于探索新型的多功能材料。

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《Crystal growth & design》 |2007年第6期|共3页
作者
Fang QR; Zhu GS; Jin Z; Xue M; Wei X; Wang DJ; Qiu SL;
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正文语种 eng
中图分类晶体学;
关键词
SECONDARY BUILDING UNITS; COORDINATION POLYMERS; NANOPOROUS MATERIAL; DESIGN; NETWORK; CHEMISTRY; CHANNELS; PTS;

机译：二级建筑;配位聚合物;纳米材料;设计;网络;化学;通道;PTS;

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1. A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carboxylate clusters [J] . Fang QR, Zhu GS, Jin Z, Crystal growth & design . 2007,第6期

机译：由五核羧酸锌簇簇构筑的具有类金刚石结构的新型金属有机骨架
2. A pillar-layered metal-organic framework based on pinwheel trinuclear zinc-carboxylate clusters; synthesis and characterization [J] . Wang Su-Juan, Alavi Mohammad Amin, Karizi Farnoosh Zare, Materials Letters . 2021,第Mara15期

机译：基于轮轮三核锌 - 羧酸纤维簇的支柱层金属 - 有机框架;合成和表征
3. A two-fold interpenetrating metal-organic framework based on tetranuclear zinc-carboxylate clusters [J] . Xiu Zhang, Guangchao Ma, Fanzhen Kong Inorganic Chemistry Communications . 2012,第Null期

机译：基于四核羧酸锌簇的互穿金属-有机骨架的两倍。
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6. Hydrogen-Bonding Linkers Yield a Large-Pore Non-Catenated Metal-Organic Framework with pcu Topology [O] . Mohammad S. Yazdanparast, Victor W. Day, Tendai Gadzikwa 2020

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A novel metal-organic framework with the diamondoid topology constructed from pentanuclear zinc-carboxylate clusters

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