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首页> 外文期刊>Crystal growth & design >Tin oxide meshes consisting of nanoribbons prepared through an intermediate phase in an aqueous solution
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Tin oxide meshes consisting of nanoribbons prepared through an intermediate phase in an aqueous solution

机译：由在水溶液中通过中间相制备的纳米带组成的氧化锡网

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摘要

Novel nanoarchitectures of SnO and SnO2 crystals that had two- and three-dimensionally meshed structures consisting of nanoribbons were prepared through Sn6O4(OH)(4) as an intermediate state. Two-dimensional meshes consisting of oriented nanoribbons of single-crystalline tin monoxide (SnO) that was 50-300 nm wide were grown via Sn6O4(OH)(4), which was initially produced at room temperature. Textured spherical particles with three-dimensional meshed nanostructures were produced at 60 degrees C in the presence of citric acid in the aqueous system. The formation of the specific architectures is ascribed to the densely branching growth of SnO crystals in a matrix of Sn6O4(OH)(4) as a reactant. The meshed nanostructures of rutile-type tin dioxide were successfully obtained by oxidation of the SnO crystals without deformation of their architectures.
机译：通过以Sn6O4（OH）（4）为中间态，制备了具有由纳米带组成的二维和三维网格结构的SnO和SnO2晶体的新型纳米结构。通过最初在室温下生产的Sn6O4（OH）（4）生长由50-300 nm宽的单晶一氧化锡（SnO）的定向纳米带组成的二维网格。在水性体系中在柠檬酸存在下于60摄氏度下产生具有三维网状纳米结构的球形球形颗粒。特定体系结构的形成归因于作为反应物的Sn6O4（OH）（4）基质中SnO晶体的密集分支生长。金红石型二氧化锡的网状纳米结构是通过氧化SnO晶体而成功获得的，而其结构没有变形。

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