Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4 '-bipyridine ligand

Liang K; Zheng HG; Song YL; Li YZ; Xin XQ

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Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4 '-bipyridine ligand

机译：基于四核巢状[WOS3Cu3]杂硫金属成矿的二级结构单元和4,4'-联吡啶配体的新型簇配位聚合物

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Two novel cluster coordination polymers, {[W4O4S12Cu12Cl2(4,4'-bipy)(12)]2Cl.4H(2)O}(n) (1) and {[(n-Bu)(4)N](2)[W2O2S6Cu6Br4(4,4'-bipy)(3)]}(n) (2) (4,4'-bipy = 4,4'-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.

机译：两种新型的簇配位聚合物{{W4O4S12Cu12Cl2（4,4'-bipy）（12）] 2Cl.4H（2）O}（n）（1）和{[（n-Bu）（4）N]（2 ）[W2O2S6Cu6Br4（4,4'-bipy）（3）]}（n）（2）（4,4'-bipy = 4,4'-bipyridine），基于四核巢状异硫代金属弹药性二级建筑单元[WOS3Cu3通过X射线衍射合成并表征。化合物1显示3D 3倍互穿的阳离子类金刚石结构，而化合物2显示1D阴离子之字形图案。它们都具有出色的三阶非线性光学（NLO）特性。

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《Crystal growth & design》 |2007年第2期|共4页
作者
Liang K; Zheng HG; Song YL; Li YZ; Xin XQ;
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正文语种 eng
中图分类晶体学;
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OPTICAL-LIMITING PROPERTIES; METAL-ORGANIC FRAMEWORKS; STRUCTURAL-CHARACTERIZATION; SUPRAMOLECULAR ARRAYS; NETWORKS; CONSTRUCTION; CAPABILITY; SEPARATION; MOLECULES; CHEMISTRY;

机译：光学限制特性;有机-有机框架;结构特征;超分子阵列;网络;结构;容量;分离;分子;化学性质;

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1. Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4 '-bipyridine ligand [J] . Liang K, Zheng HG, Song YL, Crystal growth & design . 2007,第2期

机译：基于四核巢状[WOS3Cu3]杂硫金属成矿的二级结构单元和4,4'-联吡啶配体的新型簇配位聚合物
2. Two polyoxometalate-based coordination polymers constructed from Mn(II)-4,4'-bipyridine-N,N'-dioxide building blocks and Keggin-type clusters: Syntheses, crystal structures and spectral properties [J] . Bai Y., Li M.-M., Huang-Fu Y.-J., Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2013,第Null期

机译：由Mn（II）-4,4'-联吡啶-N，N'-二氧化物结构单元和Keggin型簇构建的两种基于多金属氧酸盐的配位聚合物：合成，晶体结构和光谱性质
3. Synthesis and properties of a new (3,8)-connected pillar-layered Co(II)-based coordination polymer supported by tetranuclear secondary building units (SBUs) [J] . Guo-Ping Yang, Yuanpu Li, Dangpo Wang Inorganic Chemistry Communications . 2014,第Null期

机译：新型（3,8）连接的四核二级结构单元（SBU）支撑的柱状层状Co（II）配位聚合物的合成和性能
4. Synthesis and Photophysical Properties of Silver(I) Coordination Polymers with 4,4'-Bipiperidine and 4,4'-Bipyridine [C] . Tsubasa Yoshioka, Satoshi Sugimoto, Sota Takeuchi 日本化学会春季年会講演予稿集 . 2018

机译：用4,4'-双哌啶和4,4'-硼吡啶的银（I）配位聚合物的合成和光药性能
5. Coordination polymers and building blocks based on ditopic heteroscorpionate ligands. [D] . Santillan, Guillermo A. 2009

机译：基于对位异蝎子配体的配位聚合物和结构单元。
6. A Multifunctional Nanocage-based MOF with Tri- and Tetranuclear Zinc Cluster Secondary Building Units [O] . Zhongyuan Zhou, Xiushuang Xing, Chongbin Tian, -1

机译：多功能基于纳米笼的MOF具有三核和四核锌簇的次级构建单元。
7. Novel Cluster Coordination Polymers Based on Tetranuclear Nest-Shaped WOS3Cu3 Heterothiometallitic Secondary Building Units and 4, 4-Bipyridine Ligand [O] . -1

机译：基于四核巢形WOS3CU3杂噻吩基二级建筑单元和4,4-吡啶配体的新型簇配位聚合物

Novel cluster coordination polymers based on tetranuclear nest-shaped [WOS3Cu3] heterothiometallitic secondary building units and 4,4 '-bipyridine ligand

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