Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons

Wen LL; Lu ZD; Lin JG; Tian ZF; Zhu HH; Meng QJ

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Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons

机译：由芳族多羧酸和柔性咪唑基合成子构建的三种新型金属有机骨架的合成，结构和物理性质

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Three novel interesting coordination polymers, [Cd-3(SIP)(2)(bbi)(5)center dot 3H(2)O](n) (1), [Co-3(SIP)(2)(bix)(4)(2H(2)O)center dot 2H(2)O](n) (2), and [Cd(2,5-pydc)(2)(bix)(1.5)center dot H2O](n) (3) (SIP = 5-sulfoisophthalic acid monosodium sa bbi = 1,1'-(1,4-butanediyl)bis(imidazole); bix = 1,4-bis(imidazol-1-ylmethyl)-benzene; 2,5-pydc = pyridine-2,5-dicarboxylic acid), have been isolated under hydrothermal conditions and structurally characterized. Polymer 1 has a 3D complicated framework comprised of an infinite 1D ladder-like chain and 2D layer structure. Polymer 2 features a 3D hydrated framework with uncoordinated water molecules trapped in the pores. Polymer 3 is a 2D infinite layer framework, which is further interconnected by hydrogen-bond interactions to lead to a 3D supramolecular architecture. Compounds 1 and 3 exhibit medium-strong fluorescent emissions in the solid state at room temperature and could be significant in the field of photoactive materials.

机译：三种新颖有趣的配位聚合物，[Cd-3（SIP）（2）（bbi）（5）中心点3H（2）O]（n）（1），[Co-3（SIP）（2）（bix）（4）（2H（2）O）中心点2H（2）O]（n）（2）和[Cd（2,5-pydc）（2）（bix）（1.5）中心点H2O] [n ）（3）（SIP ＝ 5-磺基间苯二甲酸一钠盐; bbi ＝ 1，1’-（1，4-丁二基）双（咪唑）; bix ＝ 1，4-双（咪唑-1-基甲基）-苯; 2,5-pydc =吡啶-2,5-二羧酸）已在水热条件下分离并进行了结构表征。聚合物1具有3D复杂框架，该框架由无限的1D梯形链和2D层结构组成。聚合物2具有3D水化骨架，其中不协调的水分子滞留在孔隙中。聚合物3是2D无限层框架，通过氢键相互作用进一步相互连接，从而形成3D超分子体系。化合物1和3在室温下呈固态呈现中等强度的荧光发射，在光敏材料领域可能很重要。

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《Crystal growth & design》 |2007年第1期|共7页
作者
Wen LL; Lu ZD; Lin JG; Tian ZF; Zhu HH; Meng QJ;
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正文语种 eng
中图分类晶体学;
关键词
SECONDARY BUILDING UNITS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; KAGOME LATTICE; NETWORK; LIGANDS; COMPLEXES; DESIGN; PYRAZINE-2; 3-DICARBOXYLATE; FERRIMAGNET;

机译：二级建筑;配位聚合物;晶体结构;Kagome晶格;网络;配体;络合物;设计;PYRAZINE-2;3-二羧酸盐;铁磁体;

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1. Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons [J] . Wen LL, Lu ZD, Lin JG, Crystal growth & design . 2007,第1期

机译：由芳族多羧酸和柔性咪唑基合成子构建的三种新型金属有机骨架的合成，结构和物理性质
2. Five d(10) 3D metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based ligands [J] . Lin JD, Cheng JW, Du SW Crystal growth & design . 2008,第9期

机译：五个d（10）3D金属-有机骨架，由芳族多羧酸和柔性咪唑基配体构成
3. Six New Metal?Organic Frameworks Based on Polycarboxylate Acids and V-shaped Imidazole-Based Synthon: Syntheses, Crystal Structures, and Properties [J] . Hu Jinsong, Huang Liangfang, Yao Xiaoqiang, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第6期

机译：六种基于聚羧酸和V型咪唑基合成子的新型金属有机骨架：合成，晶体结构和性质
4. Syntheses, Crystal Structure and Fluorescence Property of Copper (II) Complex Constructed from 5-Sulfosalicylic Acid [C] . Liyan You, Hui Jiang, Chaohong Ma International Conference on Energy, Environment and Sustainable Development . 2017

机译：由5-磺化水杨酸构成的铜（II）复合物的合成，晶体结构和荧光性能
5. Crystalline metal-organic frameworks based on conformationally flexible phosphonic acids. [D] . Gagnon, Kevin James. 2013

机译：基于构象柔性膦酸的结晶金属有机骨架。
6. Three Novel Lanthanide Metal-Organic Frameworks (Ln-MOFs) Constructed by Unsymmetrical Aromatic Dicarboxylatic Tectonics: Synthesis Crystal Structures and Luminescent Properties [O] . Ya-Pan Wu, Dong-Sheng Li, Wei Xia, 2014

机译：非对称芳族二羧酸构造构造的三种新型镧系金属有机骨架（Ln-MOFs）：合成晶体结构和发光性质
7. Syntheses and Structures of Four d10 Metal-Organic Frameworks Assembled with Aromatic Polycarboxylate and bix bix = 1, 4-Bis(imidazol-1-ylmethyl)benzene [O] . -1

机译：用芳族多元羧酸盐和Bix组装的四个D10金属 - 有机框架的合成和结构Bix = 1,4-双（Imidazol-1-基甲基）苯

Syntheses, structures, and physical properties of three novel metal-organic frameworks constructed from aromatic polycarboxylate acids and flexible imidazole-based synthons

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