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Studies on the PEG-Assisted Hydrothermal Synthesis and Growth Mechanism of ZnO Microrod and Mesoporous Microsphere Arrays on the Substrate

机译:PEG辅助水热合成ZnO微棒和基体上介孔微球阵列的生长机理研究

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摘要

With the introduction of poly ethylene glycol (PEG) (10000), relatively well dispersed and oriented ZnO microrod arrays and ZnO microsphere arrays were successfully synthesized on unmodified indium tin oxide (Fro) substrate by a hydrothermal method. The growth behaviors of the two different kinds or ZnO arrays were experimentally investigated with variations of PEG addition and the precursor solution's concentration. The PEG-assisted growth mechanism of ZnO microrod arrays and ZnO microsphere arrays has also been carefully discussed. Both the dissolved state of PEG and the interaction between PEG and ZnO crystalline grains were found to play important roles in the fabrication of the two different ZnO structure arrays. The research on PEG-assisted growth mechanism for these two kinds of ZnO structure arrays will provide more theoretical references for preparations of ZnO one-dimensional rod arrays and other kinds of assembled structures on the substrate.
机译:随着聚乙二醇(PEG)(10000)的引入,通过水热法成功地在未改性的铟锡氧化物(Fro)衬底上合成了相对分散且取向良好的ZnO微棒阵列和ZnO微球阵列。实验研究了两种不同种类或ZnO阵列的生长行为,并观察了PEG添加和前体溶液浓度的变化。还仔细讨论了PEG辅助的ZnO微棒阵列和ZnO微球阵列的生长机理。 PEG的溶解状态以及PEG与ZnO晶粒之间的相互作用都被发现在两种不同ZnO结构阵列的制造中起着重要作用。两种ZnO结构阵列的PEG辅助生长机理的研究将为在衬底上制备ZnO一维杆阵列和其他类型的组装结构提供更多的理论参考。

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