From zero-to three-dimensional thioantimonates: [Ni(aepa)_2] _3Sb_6S_(12) (aepa = C_5H _(15)N_3 = N -(aminoethyl)-1,3-propandiamine), containing the unique [Sb_6S_(12)]~(6-) cyclic anion, [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4)

Seidlhofer B.; Djamil J.; N?ther C.; Bensch W.

首页> 外文期刊>Crystal growth & design >From zero-to three-dimensional thioantimonates: [Ni(aepa)_2] _3Sb_6S_(12) (aepa = C_5H _(15)N_3 = N -(aminoethyl)-1,3-propandiamine), containing the unique [Sb_6S_(12)]~(6-) cyclic anion, [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4)

【24h】

From zero-to three-dimensional thioantimonates: [Ni(aepa)_2] _3Sb_6S_(12) (aepa = C_5H _(15)N_3 = N -(aminoethyl)-1,3-propandiamine), containing the unique [Sb_6S_(12)]~(6-) cyclic anion, [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4)

机译：从零到三维硫代锑酸盐：[Ni（aepa）_2] _3Sb_6S_（12）（aepa = C_5H _（15）N_3 = N-（氨基乙基）-1,3-丙二胺），其中包含独特的[Sb_6S_（12））]〜（6-）环状阴离子，[Ni（aepa）_2] _6（Sb_3S_6）_2（SO _4）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The new thioantimonates [Ni(aepa)_2]_3Sb _6S_(12) (1), [Ni(aepa)_2]_6(Sb _3S_6)_2(SO_4)_3?2H _2O (2), and [Ni(aepa)_2]Sb_4S_7 (3) (aepa = C_5H_(15)N_3 = N-(aminoethyl)-1,3- propandiamine) were obtained under solvothermal conditions by slightly varying the reaction conditions. In all compounds the [Ni(aepa)_2] ~(2+) complexes were formed in situ during the chemical reactions. Compound 1 features the new unique [Sb_6S_(12)]~(6-) cyclic anion composed by vertex-linked SbS3 trigonal pyramids. This [Sb_6S_(12)]~(6-) cyclic anion represents the largest isolated thioantimonate(III) anion. In the structure of [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4)_3?2H_2O, three SbS_3 units are corner-linked to form a Sb_3S_3 hetero ring adopting a twist conformation. Additionally, the new nickel complex [Ni(aepa)_2] _2Cl_2 was isolated from the same reaction slurry and was structurally characterized. Compound 3 represents a rare example of a three-dimensional thioantimonate(III) network. The [Sb_4S _7]~(2-) anion contains large Sb_(14)S_(14) rings with dimension of 6.1 × 16.1 ?~2. The structure directing effect of the in situ formed cations is obvious because [Ni(aepa) _2]~(2+) molecules are located in pairs above and below the large rings. The first photocatalytic hydrogen evolution tests exhibit promising results for compound 3.

机译：新的硫代锑酸盐[Ni（aepa）_2] _3Sb _6S_（12）（1），[Ni（aepa）_2] _6（Sb _3S_6）_2（SO_4）_3？2H _2O（2）和[Ni（aepa）_2通过稍微改变反应条件，在溶剂热条件下获得] Sb_4S_7（3）（aepa ＝ C_5H_（15）N_3 ＝ N-（氨基乙基）-1，3-丙二胺）。在所有化合物中，[Ni（aepa）_2]〜（2+）络合物都是在化学反应中原位形成的。化合物1具有新的独特的[Sb_6S_（12）]〜（6-）环状阴离子，该阴离子由顶点连接的SbS3三角金字塔组成。该[Sb_6S_（12）]〜（6-）环状阴离子代表最大的分离硫代锑酸根（III）阴离子。在[Ni（aepa）_2] _6（Sb_3S_6）_2（SO_4）_3→2H_2O的结构中，三个SbS_3单元被角连接以形成采用扭曲构象的Sb_3S_3杂环。另外，从相同的反应浆料中分离出新的镍络合物[Ni（aepa）_2] _2Cl_2，并对其结构进行了表征。化合物3代表三维硫代锑酸盐（III）网络的罕见实例。 [Sb_4S _7]〜（2-）阴离子包含尺寸为6.1×16.1？〜2的大Sb_（14）S_（14）环。由于[Ni（aepa）_2]〜（2+）分子成对地位于大环的上方和下方，因此原位形成的阳离子具有明显的结构导向作用。首次光催化氢析出试验显示了化合物3的有希望的结果。

著录项

来源
《Crystal growth & design》 |2011年第12期|共7页
作者
Seidlhofer B.; Djamil J.; N?ther C.; Bensch W.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词

相似文献

外文文献

1. From zero-to three-dimensional thioantimonates: [Ni(aepa)_2] _3Sb_6S_(12) (aepa = C_5H _(15)N_3 = N -(aminoethyl)-1,3-propandiamine), containing the unique [Sb_6S_(12)]~(6-) cyclic anion, [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4) [J] . Seidlhofer B., Djamil J., N?ther C., Crystal growth & design . 2011,第12期

机译：从零到三维硫代锑酸盐：[Ni（aepa）_2] _3Sb_6S_（12）（aepa = C_5H _（15）N_3 = N-（氨基乙基）-1,3-丙二胺），其中包含独特的[Sb_6S_（12））]〜（6-）环状阴离子，[Ni（aepa）_2] _6（Sb_3S_6）_2（SO _4）
2. Crystal structure of aqua[μ-11,23-dimethyl-3,7,15,19-tetraazatricyclo[19.3.1.1~(9,13)]tetracosa-1(24),9(25),10,12,21,23-hexaene-25,26-diol]- (1,3-benzenedicarboxylato)dinickel(H) — methanol (1:0.75), Ni_2(H_2O)(C_(24)H_(34)N_4O_2)(C_8H_4O_4) 0.75CH_3OH [J] . Huan-Huan Chen, Ying-Ying Liu Zeitschrift fur Kristallographie. New crystal structures . 2010,第2a3期

机译：水[μ-11,23-二甲基-3,7,15,19-四氮杂三环[19.3.1.1〜（9,13）] tetracosa-1（24），9（25），10,12,21的晶体结构，23-己烯-25,26-二醇]-（1,3-苯二甲酸基）二镍（H）-甲醇（1：0.75），Ni_2（H_2O）（C_（24）H_（34）N_4O_2）（C_8H_4O_4）0.75 CH_3OH
3. Crystal structure of aqua[u-11,23-dimethy1-3,7,15,19-tetraazatricyclo[19.3.1.1~(9'13)]tetracosa-1(24),9(25),10,12,21,23-hexaene-25,26-diol]- (1,3-benzenedicarboxylato)dinickel(H) — methanol (1:0.75), Ni_2(H_2O)(C_(24)H_(34)N_4O_2)(C_8H_4O_4) · 0.75CH_3OH [J] . Huan-Huan Chen, Ying-Ying Liu Zeitschrift fur Kristallographie. New crystal structures . 2010,第3期

机译：aqua [u-11,23-dimethy1-3,7,15,19-tetraazatricyclo [19.3.1.1〜（9'13）] tetracosa-1（24），9（25），10,12,21的晶体结构，23-己烯-25,26-二醇]-（1,3-苯二甲酸基）二镍（H）—甲醇（1：0.75），Ni_2（H_2O）（C_（24）H_（34）N_4O_2）（C_8H_4O_4）· 0.75CH_3OH
4. Continuous thermogravimetric analysis during the cyclic oxidation of Ni–22Al–15Pt + 1 wt. Hf at 1200 C [O] . Kartono R., Monceau Daniel, Young David 2007

机译：Ni–22Al–15Pt + 1 wt。％Hf在1200 C循环氧化过程中的连续热重分析

From zero-to three-dimensional thioantimonates: [Ni(aepa)_2] _3Sb_6S_(12) (aepa = C_5H _(15)N_3 = N -(aminoethyl)-1,3-propandiamine), containing the unique [Sb_6S_(12)]~(6-) cyclic anion, [Ni(aepa) _2]_6(Sb_3S_6)_2(SO _4)

摘要

著录项

相似文献

相关主题

期刊订阅