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Is organic fluorine really 'not' polarizable?

机译:有机氟真的“不可”极化吗?

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摘要

The covalent chemistry of the main group element fluorine is well understood. In contrast, its noncovalent chemistry, which forms the pillar of the paradigm of supramolecular chemistry, is still in its infancy. The latter involves a complete understanding of the different interactions (both intermolecular and intramolecular) involving donor and acceptor atoms. This perspective highlights the recent developments in the understanding of noncovalent interactions in relation to organic fluorine (partially fluorinated compounds) and the versatility and importance of such interactions to the scientific community.
机译:众所周知,主族元素氟的共价化学。相比之下,构成超分子化学范式支柱的非共价化学仍处于起步阶段。后者包括对涉及供体和受体原子的不同相互作用(分子间和分子内)的完整理解。这种观点突出了对与有机氟(部分氟化的化合物)有关的非共价相互作用的理解的最新发展,以及这种相互作用对科学界的多功能性和重要性。

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