Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II

David J. Vinyard; Gary W. Brudvig

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Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II

机译：照相氧化水氧化分子机制的进展

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4 CaO ₅ cluster embedded in the PSII protein matrix, and it cycles through redox intermediates known as S _i states ( i = 0–4). Significant progress has been made in understanding the inorganic and physical chemistry of states S ₀ –S ₃ through experiment and theory. The chemical steps from S ₃ to S ₀ are more poorly understood, however, because the identity of the substrate water molecules and the mechanism of O–O bond formation are not well established. In this review, we highlight both the consensuses and the remaining challenges of PSII research.]]>

机译：<！[CDATA [光合水氧化的活性位点是照相氧化物II（PSII）反应中心的氧化复合物（OEC）。 OEC是嵌入在PSII蛋白质基质中的Mn _{4 CaO _{5 簇，并通过称为s _{i 的氧化还原中间体循环状态（ i = 0-4）。通过实验和理论了解状态S _{0 -s _{3 的无机和物理化学方面取得了重大进展。从S _{3 到S _{0 的化学步骤更差，然而，因为底物水分子的同一性和O-O键形成的机制并不良好已确立的。在本综述中，我们突出了PSII研究的共识和剩下的挑战。]]]>}}}}}}}

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来源
《Annual Review of Physical Chemistry》 |2017年第2017期|共16页
作者
David J. Vinyard; Gary W. Brudvig;
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作者单位

Department of Biological Sciences Louisiana State University Baton Rouge Louisiana 70803;

Department of Chemistry Yale University New Haven Connecticut 06520;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
photosynthesis; solar fuels; oxygen evolution;

机译：光合作用;太阳能燃料;氧气进化;

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1. Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II [J] . David J. Vinyard, Gary W. Brudvig Annual Review of Physical Chemistry . 2017,第期

机译：照相氧化水氧化分子机制的进展
2. Water oxidation mechanism in photosystem II, including oxidations, proton release pathways, O-O bond formation and O2 release. [J] . Per E M Siegbahn Biochimica et biophysica acta. Bioenergetics . 2013,第8a9期

机译：光系统II中的水氧化机理包括氧化，质子释放途径，O-O键形成和O2释放。
3. Theory of chemical bonds in metalloenzymes XXI. Possible mechanisms of water oxidation in oxygen evolving complex of photosystem II [J] . Yamaguchi Kizashi, Shoji Mitsuo, Isobe Hiroshi, Molecular physics . 2018,第5a6期

机译：金属酶XXI中化学键理论。照相系统II的氧不应复合物中的水氧化机制
4. PHOTOINDUCED INTRAMOLECULAR ELECTRON TRANSFER IN A Mn_2~(II,II)-RU~(II)-(NDI)_2 MOLECULAR TRIAD LEADING TO A LONG-LIVED CHARGE SEPARATED STATE - MIMICKING THE ELECTRON TRANSFER CHAIN IN PHOTOSYSTEM-II [C] . Nizamuddin Shaikh, Olof Johansson, Magnus Borgstrom, International Congress of Photosynthesis . 2005

机译：Mn_2〜（II，II）中的光突出的分子内电子转移 - （II） - （NDI） - （NDI）_2分子三合会导致长寿命电荷分离状态 - 模仿照相系统-II中的电子转移链
5. Proton transfer reactions in photosynthetic water oxidation: Second sphere ligands of the manganese cluster modulate the water oxidation mechanism of photosystem ii. [D] . Dilbeck, Preston Lee. 2012

机译：光合水氧化中的质子转移反应：锰团簇的第二球配体调节光系统ii的水氧化机理。
6. Functional implications on the mechanism of the function of photosystem II including water oxidation based on the structure of photosystem II. [O] . Petra Fromme, Jan Kern, Bernhard Loll, 2002

机译：对光系统II功能机理的功能含义包括基于光系统II结构的水氧化。
7. 1SAA-07 Development of molecular catalysts for water oxidation toward artificial photosynthesis(1SAA Molecular mechanism of light-driven water oxidation : photosystem II and artificial photosynthesis,Symposium,The 51th Annual Meeting of the Biophysical Society of Japan) [O] . Masayuki Yagi 2013

机译：1SAA-07分子催化剂的水氧化朝着人造光合作用（1SAA光电水氧化的分子机制：光系统II和人工光合作用，研讨会，日本生物物理学会的第51次年会）

Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II

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