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首页> 外文期刊>Annual Review of Physical Chemistry >Connections Between Theory and Experiment for Gold and Silver Nanoclusters
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Connections Between Theory and Experiment for Gold and Silver Nanoclusters

机译：黄金和银纳米能器理论与实验之间的联系

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摘要

Ligand-stabilized gold and silver nanoparticles are of tremendous current interest in sensing, catalysis, and energy applications. Experimental and theoretical studies have closely interacted to elucidate properties such as the geometric and electronic structures of these fascinating systems. In this review, the interplay between theory and experiment is described; areas such as optical absorption and doping, where the theory-experiment connections are well established, are discussed in detail; and the current status of these connections in newer fields of study, such as luminescence, transient absorption, and the effects of solvent and the surrounding environment, are highlighted. Close communication between theory and experiment has been extremely valuable for developing an understanding of these nanocluster systems in the past decade and will undoubtedly continue to play a major role in future years.
机译：配体稳定的金和银纳米粒子对传感，催化和能源应用具有巨大的电流感兴趣。 实验和理论研究密切相互作用，以阐明这些迷人系统的几何和电子结构等性质。 在本文中，描述了理论和实验之间的相互作用; 详细讨论了理论实验连接的光学吸收和掺杂等领域; 并且突出了较新的研究领域中这些连接的当前状态，例如发光，瞬态吸收和溶剂和周围环境的影响，并被突出。 在过去十年中，理论和实验之间的密切沟通对于开发对这些纳米光幕系统的理解非常有价值，无疑将在未来几年中继续发挥重要作用。

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