Photoredox reactions of binuclear iron(II) and (III) disulfide complexes. Disulfide as CT acceptor and donor

Vogler Arnd

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Photoredox reactions of binuclear iron(II) and (III) disulfide complexes. Disulfide as CT acceptor and donor

机译：光核铁（II）和（III）二硫化物复合物的光致毒剂反应。二硫化物作为CT受体和供体

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In analogy to peroxide, disulfide is an oxidant as well as a reductant. Accordingly, as a ligand of a reducing metal center, low-energy MLCT transitions can occur, while with oxidizing metals low-energy LMCT transitions should be observed. Such MLCT and LMCT excitations are expected to induce redox reactions. The complexes [CpFe(II)(CO)(2)](2)mu-S-2 (Cp=C5H5) and {[Fe(III)(CN)(5)](2)mu-S-2}(6-) are suitable examples to explore this behavior. (C) 2017 Elsevier B.V. All rights reserved.

机译：与过氧化物类似，二硫化物是氧化剂以及还原剂。因此，作为还原金属中心的配体，可能会发生低能量MLCT转变，而应该观察到氧化金属低能量LMCT转变。预计这种MLCT和LMCT激发会诱导氧化还原反应。复合物[CPFE（II）（CO）（2）]（2）MU-S-2（CP = C5H5）和{[Fe（III）（CN）（5）]（2）MU-S-2} （6-）是探索这种行为的合适例子。（c）2017 Elsevier B.v.保留所有权利。

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《Inorganic Chemistry Communications》 |2017年第2017期|共3页
作者
Vogler Arnd;
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作者单位

Univ Regensburg Inst Inorgan Chem Regensburg Germany;

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原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Iron complexes; Disulfide complexes; Photoredox reactions; MLCT; LMCT;

机译：铁络合物;二硫化物复合物;摄影毒剂反应;MLCT;LMCT;

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Photoredox reactions of binuclear iron(II) and (III) disulfide complexes. Disulfide as CT acceptor and donor

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