Influencing the outcome: Diorganotin(IV) ladder to macrocycle conversion through solvent selection

Tushar S. Basu Baul; Dhrubajyoti Dutta; Andrew Duthie; M. Fátima C. Guedes da Silva

首页> 外文期刊>Inorganic Chemistry Communications >Influencing the outcome: Diorganotin(IV) ladder to macrocycle conversion through solvent selection

【24h】

Influencing the outcome: Diorganotin(IV) ladder to macrocycle conversion through solvent selection

机译：影响结果：Diorgonotin（IV）通过溶剂选择宏循环转化梯

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract

The self-assembly of tetrabutyldistannoxane ladder {[nBu2Sn(LH)]2O}21upon crystallization in xylene affords the novel cyclic dimer [nBu(LxH)Sn]22, featuring a 22-membered macrocycle. The dimer also contains a 2-fold linkage of neighbouring units via intermolecular Sn-O contacts, giving rise to polymeric 1D chains in which the tin atoms assume pentagonal bipyramidal environments by means of additional Sn-Ocatecholatecontacts.

Graphical abstract

Unprecedented formation of dibutyltin(IV)-macrocycle via dibutyltin(IV) ladder in presence of xylene is described.

Display Omitted

Highlights

?A novel 22-membered dinuclear metello-macrocycle has been synthesized.

?Metello-macrocycle is the first example of tin(IV) complex which is achieved by simple decarbonylation of dibutyltin ladder.

?Coordination pattern at the Sn(IV) centers has been established by spectroscopic studies and X-ray diffraction.

]]>

机译：<！[cdata [

抽象

TetabutyLDistannOxane梯子的自组装{[ n bu 2 sn（lh）] 2 o} 2> 2 1 在二甲苯中结晶后，新型环状二聚体[ N bu（l x h）sn] 2 2 ，具有22元宏观。二聚体还含有通过分子间SN-O触点的相邻单元的2倍连接，从而产生聚合物1D链，其中锡原子通过附加的SN-O CateCholate 触点。 < CE：its-title id =“st0010”>图形摘要

在二甲苯存在下，通过二丁基锡（IV）梯形梯形前所未有的二丁基锡（IV）形成。

突出显示

？新颖的22元核Metello-macrocycle已被合成。

< CE：标签>？ Metello-Macrocycle是锡（IV）复合物的第一例，其通过简单的二丁基薄蛋白梯的简单脱羰。< / ce：para>

？ SN（IV）中心的协调模式已经通过光谱研究和X射线衍射建立。 ]]>

著录项

来源
《Inorganic Chemistry Communications》 |2017年第2017期|共4页
作者
Tushar S. Basu Baul; Dhrubajyoti Dutta; Andrew Duthie; M. Fátima C. Guedes da Silva;
展开▼
作者单位

Centre for Advanced Studies in Chemistry North-Eastern Hill University;

Centre for Advanced Studies in Chemistry North-Eastern Hill University;

School of Life and Environmental Science Deakin University;

Centro de Química Estrutural Complexo I Instituto Superior Técnico Universidade de Lisboa;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Organotin(IV); Self-assembly; Macrocycle; Spectroscopy; X-ray diffraction;

机译：有机锡（IV）;自组装;宏观;光谱;X射线衍射;

相似文献

外文文献
中文文献
专利

1. Influencing the outcome: Diorganotin(IV) ladder to macrocycle conversion through solvent selection [J] . Tushar S. Basu Baul, Dhrubajyoti Dutta, Andrew Duthie, Inorganic Chemistry Communications . 2017,第期

机译：影响结果：Diorgonotin（IV）通过溶剂选择宏循环转化梯
2. Synthesis and Characterization of Nanometric Pure Phase SnO2Obtained from Pyrolysis of Diorganotin(IV) Derivatives of Macrocycles [J] . MalaNath, P. K.Saini International Scholarly Research Notices . 2012,第4期

机译：大环二有机锡（IV）衍生物热解获得的纳米纯相SnO2的合成与表征
3. Synthesis and Characterization of Nanometric Pure Phase SnO2Obtained from Pyrolysis of Diorganotin(IV) Derivatives of Macrocycles [J] . MalaNath, P. K.Saini International Scholarly Research Notices . 2012,第59期

机译：大环二有机锡（IV）衍生物热解获得的纳米纯相SnO2的合成与表征
4. Synthesis and Characterisation of Diorganotin(IV) Complexes of 3,4-Dihydroxybenzaldehyde Semicarbazone [C] . Nasry Jassim Hussien, Yang Farina, Mohamad Jaber Al-Jebooric UKM FST Postgraduate Colloquium . 2016

机译：3,4-二羟基苯甲醛氨基脲（IV）复合物的合成与表征
5. Solvent system selection for xylooligosaccharides separation by centrifugal partition chromatography using conductor-like screening model for real solvents [D] . Zhang, He 2014

机译：离心分离色谱法分离木糖寡糖的溶剂系统选择，采用导体样筛查模型进行真实溶剂
6. Inhibition of Cytochrome P450 3A in Rat Liver by the Diorganotin (IV) Compound di-n-Butyl-di-(4-chlorobenzo-hydroxamato)tin (IV) and Its Probable Mechanism [O] . Yunxia Zhang, Yunlan Li, Qingshan Li 2012

机译：Diorganotin（IV）化合物二正丁基-二-（4-氯苯并-羟肟基）锡（IV）对大鼠肝脏中细胞色素P450 3A的抑制作用及其可能机理
7. LXXVIII.—Experiments on the Walden inversion. Part IV. The influence of the solvent on the sign of the product in the conversion of phenylchloroacetic acid to phenylaminoacetic acid—(continued) [O] . George Senter, Harry Dugald Keith Drew 1916

机译：Lxxviii.-沃尔登反演的实验。第四部分。溶剂对产物标志的影响在苯基氯乙酸转化为苯基氨基乙酸 - （续）
8. Oxy and Thio Phosphorus Acid Derivatives of Tin. 4. Diorganotin (IV) Bis(Dithiophosphate) Esters [R] . Lefferts, J. L., Molloy, K. C., Zuckerman, J. J., 1980

机译：锡的氧化和硫代磷酸衍生物。 4.二有机锡（IV）双（二硫代磷酸酯）酯

Influencing the outcome: Diorganotin(IV) ladder to macrocycle conversion through solvent selection

摘要

著录项

相似文献

相关主题

期刊订阅