Experimental study on interconversion between cubic MOF-5 and square MOF-2 arrays

Luca Schweighauser; Koji Harano; Eiichi Nakamura

首页> 外文期刊>Inorganic Chemistry Communications >Experimental study on interconversion between cubic MOF-5 and square MOF-2 arrays

【24h】

Experimental study on interconversion between cubic MOF-5 and square MOF-2 arrays

机译：立方体MOF-5和方形MOF-2阵列相互互连的实验研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract

The synthesis of metal–organic frameworks (MOFs) often exhibits unpredictable complexity. Here, we report that MOF-5 formation at 120°C takes a pathway different from the MOF-2-like crystal formation at 95°C, and suggest that their interconversion requires degradation of the whole crystal structure.

Graphical abstract

Display Omitted

Highlights

?Formation of cubic MOF-5 and layered MOF-2 takes place by different pathways.

?Interconversion is only possible through complete destruction of crystal structure.

?The study implies that capping agents facilitate the formation of MOF-5 and MOF-2.

]]>

机译：<！[cdata [

抽象

金属 - 有机框架（MOF）的合成通常表现出不可预测的复杂性。在这里，我们认为120°C的MOF-5形成具有与95℃的MOF-2样晶体形成不同的途径，并表明它们的相互转换需要劣化整个晶体结构。

图形抽象

显示省略

突出显示

< CE：标签>？立方MOF-5的形成和分层MOF-2通过不同的路径进行。

？通过完全破坏晶体结构仅实现互联。

？研究意味着封装代理促进了形成mof-5和mof-2。 ]]]>

著录项

来源
《Inorganic Chemistry Communications》 |2017年第2017期|共4页
作者
Luca Schweighauser; Koji Harano; Eiichi Nakamura;
展开▼
作者单位

Department of Chemistry Graduate School of Science The University of Tokyo;

Department of Chemistry Graduate School of Science The University of Tokyo;

Department of Chemistry Graduate School of Science The University of Tokyo;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Metal-organic frameworks (MOF); Structural interconversion; Crystal; Prenucleation clusters; Zinc;

机译：金属有机框架（MOF）;结构间隔;晶体;PRENUCLEATION簇;锌;

相似文献

外文文献
中文文献
专利

1. Experimental study on interconversion between cubic MOF-5 and square MOF-2 arrays [J] . Luca Schweighauser, Koji Harano, Eiichi Nakamura Inorganic Chemistry Communications . 2017,第期

机译：立方体MOF-5和方形MOF-2阵列相互互连的实验研究
2. Experimental and simulation study of missing matching peaks in Nb thin films with square pinning arrays [J] . R. Cao, Lance Horng, T. C. Wu, Journal of Applied Physics . 2011,第8PTa1期

机译：具有方形钉扎阵列的Nb薄膜中缺少匹配峰的实验和模拟研究
3. Experimental studies of extraordinary light transmission through periodic arrays of subwavelength square and rectangular holes in metal films [J] . 华一磊, 傅晋欣, 李江艳, 中国物理：英文版 . 2010,第004期

机译：通过金属膜中亚波长方孔和矩形孔的周期性阵列实现非凡光传输的实验研究
4. Numerical and experimental studies of a dual-polarized planar connected-array antenna for the Australian Square Kilometer Array Pathfinder [C] . Hay, S., Cooray, F., O'Sullivan, J., IEEE Antennas and Propagation Society International Symposium;APSURSI '09 . 2009

机译：澳大利亚平方公里阵列探路器的双极化平面连接阵列天线的数值和实验研究
5. Cubic spline finite element method for solving Poisson's equation on a square. [D] . Beck, Stephanie. 2014

机译：三次样条有限元方法，用于求解正方形的泊松方程。
6. Atomistic structures and dynamics of prenucleation clusters in MOF-2 and MOF-5 syntheses [O] . Junfei Xing, Luca Schweighauser, Satoshi Okada, -1

机译：MOF-2和MOF-5合成中预核簇的原子结构和动力学
7. Experimental study of the propagation of a far-field disturbance in the turbulent flow through square array tube banks [O] . Luiz A. Magalhães Endres, Sergio Viçosa Möller 2009

机译：方管阵列湍流中远场扰动传播的实验研究
8. Fortran IV Least Squares Computer Program for the Profile Refinement of Cubic Powder Diffraction Patterns with Cubic Harmonic Functions. [R] . Taylor, J. C. 1980

机译：Fortran IV最小二乘计算机程序，用于具有立方谐波函数的立方粉末衍射图案的轮廓细化。

Experimental study on interconversion between cubic MOF-5 and square MOF-2 arrays

摘要

著录项

相似文献

相关主题

期刊订阅