Lanthanide(III)-organic extended frameworks based on cubic [Ln(4)(mu(3)-OH)(4)] clusters: Syntheses, structures and application as fluorescent sensor

Zhou Jie; Zhu Ting-Ting; Han Jie; Chen Xu-Dong

首页> 外文期刊>Inorganic Chemistry Communications >Lanthanide(III)-organic extended frameworks based on cubic [Ln(4)(mu(3)-OH)(4)] clusters: Syntheses, structures and application as fluorescent sensor

【24h】

Lanthanide(III)-organic extended frameworks based on cubic [Ln(4)(mu(3)-OH)(4)] clusters: Syntheses, structures and application as fluorescent sensor

机译：基于立方[LN（4）（mu（3）-OH）（4）]簇的镧系元素（III） - 基于立方[LN（4）（4）]的延伸框架：合成，结构和应用作为荧光传感器

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Three new lanthanide coordination polymers based on 4,4'-disulfo-[1,1'-diphenyl]-2,2'-dicarboxylate acid (H4DSDC) have been synthesized, namely {[Ln(4)(DSDC)(1.5)(COO)(2)(OH)(4)(H2O)(7)]center dot 10H(2)O}(n) (Ln = Tb, Eu or Sm), which are characterized to be isostructural. The cubic [Ln(4)(mu(3)-OH)(4)] species in these complexes are connected to adjacent one through coordination bridging from a pair of formate groups to generate double-cubane-shaped moieties as secondary building units, which are linked by tetraanionic DSDC4- ligands to form a 3D framework structure featuring (3(12).4(32).5(40).6(33).7(2).8)(3(2).4(3).5)(3) topology. The Tb(III) complex proves to be a highly selective and sensitive turn-off fluorescent sensor for Fe3+ ion.

机译：已经合成了基于4,4'-二磺酰基] -2,2'-二羧酸甲酸（H4DSDC）的三种新的镧系元素配位聚合物，即{[LN（4）（DSDC）（1.5）（COO）（2）（OH）（4）（H 2 O）（7）]中心点10H（2）O}（N）（LN = TB，EU或SM），其特征是是isostrontuctuctory的。这些配合物中的立方[Ln（3）（4）（mu（3）-OH）（4）]通过从一对甲酸酯基团的配位桥接连接到相邻的物种，以产生作为二级建筑单元的双层形状的部分，由TetraAnionic DSDC 4-配体连接以形成3D框架结构（3（12）.4（32）.5（40）。6（33）.7（2）。8）（3（2）.4 （3）.5）（3）拓扑。 TB（III）复合物被证明是Fe3 +离子的高度选择性和敏感的荧光传感器。

著录项

来源
《Inorganic Chemistry Communications》 |2019年第1期|共4页
作者
Zhou Jie; Zhu Ting-Ting; Han Jie; Chen Xu-Dong;
展开▼
作者单位

Nanjing Normal Univ Jiangsu Collaborat Innovat Ctr Biomed Funct Mat Sch Chem &

Mat Sci Nanjing 210023 Jiangsu Peoples R China;

Nanjing Normal Univ Jiangsu Collaborat Innovat Ctr Biomed Funct Mat Sch Chem &

Mat Sci Nanjing 210023 Jiangsu Peoples R China;

Open Univ Hong Kong Sch Sci &

Technol Kowloon Hong Kong Peoples R China;

Nanjing Normal Univ Jiangsu Collaborat Innovat Ctr Biomed Funct Mat Sch Chem &

Mat Sci Nanjing 210023 Jiangsu Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Lanthanide complex; Coordination polymer; Metal-organic framework; Luminescent sensor; Fe3+;

机译：镧系元素化合物;配位聚合物;金属 - 有机框架;发光传感器;FE3 +;

相似文献

外文文献
中文文献
专利

1. Lanthanide(III)-organic extended frameworks based on cubic [Ln(4)(mu(3)-OH)(4)] clusters: Syntheses, structures and application as fluorescent sensor [J] . Zhou Jie, Zhu Ting-Ting, Han Jie, Inorganic Chemistry Communications . 2019,第1期

机译：基于立方[LN（4）（mu（3）-OH）（4）]簇的镧系元素（III） - 基于立方[LN（4）（4）]的延伸框架：合成，结构和应用作为荧光传感器
2. Diversity of lanthanide(III)-organic extended frameworks with a 4,8-disulfonyl-2,6-naphthalenedicarboxylic acid ligand: Syntheses, structures, and magnetic and luminescent properties [J] . Liu Q.-Y., Wang W.-F., Wang Y.-L., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第4期

机译：具有4,8-二磺酰基-2,6-萘二甲酸配体的镧系元素（III）-有机扩展骨架的多样性：合成，结构以及磁性和发光性质
3. Diversity of lanthanide(III)-organic extended frameworks with a 4,8-disulfonyl-2,6-naphthalenedicarboxylic acid ligand: Syntheses, structures, and magnetic and luminescent properties [J] . Liu Q.-Y., Wang W.-F., Wang Y.-L., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第4期

机译：具有4,8-二磺酰基-2,6-萘二甲酸配体的镧系元素（III）-有机扩展骨架的多样性：合成，结构以及磁性和发光性质
4. Ordered nanopolymer structures including lanthanide-organic frameworks: Hydrothermal synthesis, characterization and investigation of their thermal and luminescence properties [C] . Burak Ay, Emel Yildiz, Jon Zubieta 2017 IEEE 7th International Conference Nanomaterials: Application amp; Properties . 2017

机译：包括镧系元素-有机骨架在内的有序纳米聚合物结构：水热合成，表征及其热性质和发光性质的研究
5. Syntheses of Luminescent Lanthanide (III) – Mesoporous Silica Hybrid Materials for Sensing Volatile Organic Compound [D] . Kyei, Isaac. 2019

机译：发光镧系元素（III） - 中孔二氧化硅杂化材料，用于检测挥发性有机化合物
6. Two Lanthanide Metal–Organic Frameworks Based on Semi-Rigid T-Shaped Tricarboxylate Ligand: Syntheses Structures and Properties [O] . Yun-Shan Xue, Zhuo-Lin Chen, Youzhen Dong, 2019

机译：基于半刚性T形三羧酸酯配体的两个镧系元素金属有机骨架：合成结构和性质
7. Microporous Hexanuclear Ln(III) Cluster-Based MetalOrganic Frameworks: Color Tunability for Barcode Application and Selective Removal of Methylene Blue [O] . -1

机译：微孔六核LN（III）基于簇的金属有机框架：条形码应用的颜色可调性和选择性除去亚甲基蓝色
8. Syntheses of Divalent Lanthanide Tetradecahydrodecaborates and Decahydrodecaborates. The X-ray Crystal Structure of (CH3CN)6Yb(Mu-H)2B10H12.2CH3CN. [R] . White, J. P., Deng, H. B., Shore, S. G. 1989

机译：二价镧系十四氢十二碳酸盐和十氢癸醚的合成。（CH3CN）6Yb（mu-H）2B10H12.2CH3CN的X射线晶体结构。

Lanthanide(III)-organic extended frameworks based on cubic [Ln(4)(mu(3)-OH)(4)] clusters: Syntheses, structures and application as fluorescent sensor

摘要

著录项

相似文献

相关主题

期刊订阅