Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

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Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

机译：在结构刚性的钴中心催化氢化CO2

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A diphosphinoamido cobalt scaffold was employed for studying catalytic CO2 hydrogenation. Particularly, the dissociative ligand loss of a cobalt catalyst induced by a formate product has been investigated. A structurally rigidified ligand leads to the reduction of the basicity of an amido moiety of a cobalt complex, thus revealing higher catalyst performance relative to the original ligand. With a robust N-Co moiety, the hydrolytic stability of the catalyst toward an accumulated conjugate acid [DBUH][OCHO] has been dramatically improved.

机译：使用二磷酸二磷酸二磷酸钴支架用于研究催化CO 2氢化。特别是，研究了由甲酸酯产物诱导的钴催化剂的离防配体损失。在结构上刚性的配体导致钴复合物的酰胺部分的碱度的降低，从而揭示相对于原始配体的催化剂性能更高。通过稳健的N-CO部分，催化剂朝向累积的缀合物酸ε[DBUH] [OCHO]的水解稳定性已显着改善。

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《Inorganic Chemistry Frontiers》 |2020年第9期|共6页
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1. Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center [J] . Inorganic Chemistry Frontiers . 2020,第9期

机译：在结构刚性的钴中心催化氢化CO2
2. A Rational Approach to Catalytic Enantioselective Enolate Alkylation Using a Structurally Rigidified and Defined Chiral Quaternary Ammonium Salt under Phase Transfer Conditions [J] . E. J. Corey, Feng Xu, Mark C. Noe Journal of the American Chemical Society . 1997,第50期

机译：在相转移条件下使用结构刚性和定义的手性季铵盐催化对映选择性烯醇盐烷基化的合理方法
3. Hydrogen bonding principles in inclusion compounds of triphenylsilanol and pyrrolidine: Synthesis and structural features of [(Ph3SiOH)(4)center dot HN(CH2)(4)] and [Ph3SiOH center dot HN(CH2)(4)center dot CH3CO2H] [J] . Bauer Jonathan O., Strohmann Carsten Journal of Organometallic Chemistry . 2015,第Null期

机译：三苯基硅烷醇和吡咯烷的包合物中的氢键原理：[（Ph3SiOH）（4）中心点HN（CH2）（4）]和[Ph3SiOH中心点HN（CH2）（4）中心点CH3CO2H的合成和结构特征
4. Supported Cobalt Catalysts with Preferentially Exposed Crystal Facets for CO2 Hydrogenation [C] . Cun Wen, Juan Jimenez, Maryorie Santos AIChE Annual Meeting . 2016

机译：支持的钴催化剂，其优先暴露的CO 2氢化晶面
5. CO2 Hydrogenation to Synthetic Fuel Via Modified Fischer-Tropsch Process Using Cobalt-Based Catalysts [D] . Khangale, Phathutshedzo Rodney. 2019

机译：使用钴基催化剂通过改性的Fischer-Tropsch方法对合成燃料的CO 2氢化
6. Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO2 Hydrogenation: Integrated Reaction and Catalyst Separation for CO2‐Scrubbing Solutions [O] . Martin Scott, Dr. Beatriz Blas Molinos, Christian Westhues, -1

机译：催化CO2加氢合成格式的水两相体系：CO2洗涤溶液的集成反应和催化剂分离
7. l. The Reduction Waves of Cobalt Concerning to the Brdicka's Catalytic Hydrogen-Wave The Studies on Brdicka's Catalytic Hydrogen-Wave [O] . Hiroshi SUNAHARA 1961

机译：湖关于Brdicka催化氢波的钴的减少波对Brdicka催化氢波的研究
8. Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina Co hydrogenation catalysts. Final progress report, August 1, 1987--July 31, 1990 [R] . Bartholomew, C. H. 1990

机译：分散和载体对钴/氧化铝Co加氢催化剂吸附，催化和电子性能的影响。最终进展报告，1987年8月1日 - 1990年7月31日

Catalytic hydrogenation of CO2 at a structurally rigidified cobalt center

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